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- W4311753465 abstract "ZnO-decorated ZnFe2O4 nanoparticles were synthesized for photoelectrocatalytic applications. Additionally, the effects of the nanoparticle decoration on the rectangular ZnO nanosheet surface on the structure, morphology and kinetic mechanism of the synthesized samples were investigated. The decorated ZnO nanosheets exhibited enhanced charge kinetics in a 0.1 M KOH electrolyte, which could be due to the low charge transfer resistance of 34.08 Ω and solution resistance of 1.56 Ω to the electrolyte under illumination. The highest photo-induced current achieved was 2.18 mAcm−2 in the light state in a 0.1 M KOH solution among other catalysts. The achieved current density for ZnO decorated ZnFe2O4 nanoparticles was ∼727 times higher than that of pristine ZnO nanostructures owing to the presence of numerous active sites, the electronic band structure, substantial decrement in the kinetic resistances, limiting and exchange current densities of +0.18, and −1.35 mAcm−2, and low Tafel slopes of 54.1 mVdec-1. Furthermore, a significant effect of the applied potential on photocurrent generation in the catalysts in the light states was observed. The maximum current was achieved at an applied voltage of 0.5 V for ZnO decorated with ZnFe2O4 nanoparticles with that for the ZnO and ZnFe2O4 samples. Therefore, anodes of ZnO decorated with ZnFe2O4 nanoparticles were proven to achieve stable photocurrent generation via electrochemical activity." @default.
- W4311753465 created "2022-12-28" @default.
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- W4311753465 date "2023-01-01" @default.
- W4311753465 modified "2023-10-16" @default.
- W4311753465 title "ZnFe2O4 nanoparticles decorated on rectangular ZnO nanosheets for enhanced photo-induced current generation via photoelectrochemical process" @default.
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- W4311753465 doi "https://doi.org/10.1016/j.jelechem.2022.117075" @default.
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