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- W4311763671 abstract "Two-coordinate silylamido complexes of nickel and copper rapidly react with CO2 to selectively form a new cyanate ligand along with hexamethyldisiloxane byproducts. Mechanistic insight into these reactions was obtained from the synthesis of proposed intermediates, several silyl- and phenyl- substituted amido analogues, and their subsequent reactivity with CO2. These studies suggest that a unique intramolecular double silyl transfer step facilitates CO2 deoxygenation, which likely contributes to the rapid rates of reaction. The deoxygenation reactions create a platform for a synthetic cycle in which copper amido complexes convert CO2 to organic silylcarbamates." @default.
- W4311763671 created "2022-12-28" @default.
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- W4311763671 date "2022-12-14" @default.
- W4311763671 modified "2023-09-24" @default.
- W4311763671 title "Redox-Neutral Transformations of Carbon Dioxide Using Coordinatively Unsaturated Late Metal Silyl Amide Complexes" @default.
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- W4311763671 doi "https://doi.org/10.1021/acs.inorgchem.2c03453" @default.
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