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- W4311767477 abstract "A simple thiomorpholine-based fluorescent probe was designed and synthesized by combining thiomorpholine (TM) and nitrobenzenoselenadiazoles fluorophore (NBD-Se). The thiomorpholine group quenches the fluorescence of NBD-Se efficiently through the photoinduced electron transfer (PET) effect. Hypochlorous acid (HOCl) oxidizes the NBD-Se-TM probe to its fluorescent S-oxide (NBD-Se-TSO) with a 1:1 stoichiometry. The desirable features of NBD-Se-TM for detecting HOCl in aqueous solutions, such as its high sensitivity and selectivity, reliability at physiological pH, and rapid fluorescence response, enabled its application in the detection of HOCl produced by myeloperoxidase. The results proved that NBD-Se-TM is a promising fluorescent probe that can be used in screening assays for MPO inhibitors. Its high reaction rate constant with HOCl (2k = 2.0 × 107M-1s-1) indicates the possibility of application in more complex biological systems." @default.
- W4311767477 created "2022-12-28" @default.
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- W4311767477 date "2023-03-01" @default.
- W4311767477 modified "2023-10-16" @default.
- W4311767477 title "A thiomorpholine-based fluorescent probe for the far-red hypochlorous acid monitoring" @default.
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- W4311767477 doi "https://doi.org/10.1016/j.saa.2022.122193" @default.
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