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- W4311768184 abstract "The review are summarized and analyzed structural data of over fifty monomeric complexes of Pt(κ3–P1C1P2)X (X = H, OL, NL, CL, Cl, Br or I) and Pt(κ3–P1P2C1)Cl, types. These complexes crystallized in four crystal systems: tetragonal (x1), orthorhombic (x7), triclinic (x17), and monoclinic (x30). The inner coordination spheres are built up by heterotridentate (P1/C1/P2, P1/P2/C1) with monodentate (H, OL, NL, CL, Cl, Br or I) donor ligands. Each heterotridentate ligands form wide variety of two metallocyclic rings with common C1 atom in 53 complexes and P2 atom in 2 complexes. The effect of both electronic and steric factors influences on the l-Pt-L bite angles. In generally, an inner coordination sphere in the complexes with P1/C1/P2 donor ligands have trans-configuration, with P1/P2/C1 donor ligands cis configuration. The data are compared and discussed with those of Pt(κ3–P1/O1/P2)(X) (X = OL, NL, or P3L) and Pt(κ3–P1/N1/P2)(X) (X = H, NL, CL, Cl, P3L, Br or I)." @default.
- W4311768184 created "2022-12-28" @default.
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- W4311768184 date "2023-03-01" @default.
- W4311768184 modified "2023-09-30" @default.
- W4311768184 title "Heterotridentate organophosphines in Pt(κ3–P1C1P2)(X), (X=H, OL, NL, CL, Cl, Br or I) and Pt(κ3–P1P2C1)(Cl) derivatives-structural aspects" @default.
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- W4311768184 doi "https://doi.org/10.1016/j.molstruc.2022.134768" @default.
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