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- W4311769918 endingPage "156070" @default.
- W4311769918 startingPage "156070" @default.
- W4311769918 abstract "The high self-corrosion rate of Mg in aqueous electrolyte generates H2, which is the main impediment to restrict the utilization of Mg-air batteries. However, organic/inorganic hybrid electrolyte is prone to reduce the Mg degradation. Herein, the effect of different ethanol fractions in water with 0.6 M NaCl on corrosion behavior of Mg and battery discharge performances is demonstrated. The significant corrosion inhibition in a high content of ethanol (≥20 vol%) in electrolyte is attributed to the formation of a thinner, more corrosion protective layer enriched in magnesium oxide as demonstrated by scanning electron microscopy, X-ray photoelectron spectroscopy and time-of-flight secondary ion mass spectrometry. Contrarily, in water-based electrolyte a thick, porous and rough layer principally composed of magnesium hydroxide is formed. By varying the ethanol to water fraction in the electrolyte in full battery cell, it is shown that even a small ethanol content (≤ 5 vol%), can greatly enhance the electrochemical performances of Mg anode. Within several ethanol content, 0.5 vol% demonstrates the best performances with a limited corrosion rate and greatly improves the discharge performance and the battery lifetime. It is demonstrated here that application of inorganic/organic dual electrolyte is a promising and easy way towards a well-controlled Mg anode reactivity and improved performances of Mg-air battery." @default.
- W4311769918 created "2022-12-28" @default.
- W4311769918 creator A5001189548 @default.
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- W4311769918 creator A5089897401 @default.
- W4311769918 date "2023-03-01" @default.
- W4311769918 modified "2023-09-25" @default.
- W4311769918 title "Probing Mg anode interfacial and corrosion properties using an organic/inorganic hybrid electrolyte" @default.
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- W4311769918 doi "https://doi.org/10.1016/j.apsusc.2022.156070" @default.
- W4311769918 hasPublicationYear "2023" @default.
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