FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4311771908> ?p ?o ?g. }

• W4311771908 endingPage "127127" @default.
• W4311771908 startingPage "127127" @default.
• W4311771908 abstract "In the present work, the chemical coupling between moist CO oxidation and transformation of gaseous potassium salts (KCl or KOH) in the presence and absence of SO2 was investigated experimentally and through chemical kinetic modeling. The experiments were performed in a laminar flow quartz reactor at temperatures ranging from 873 to 1473 K. The experimental results showed that both KCl and KOH inhibited CO oxidation, but addition of SO2 reduced the inhibiting effect by sulfating the potassium. The degree of sulfation of KCl and KOH by SO2 was evaluated by EDX analysis of the aerosols collected downstream in a filter. Also, the consumption of SO2 and, for KCl, the formation of HCl were indications of the level of sulfation. The results indicated that KCl was only sulfated to a small degree, consistent with the observation that addition of SO2 had little effect on the inhibition of CO oxidation by KCl. Contrary to this, the captured KOH particles were fully sulfated according to the EDX results; however, most of the KOH was captured on the quartz reactor surface, forming potassium silicates. The experimental results were interpreted in terms of a chemical kinetic model. Thermodynamic data for key potassium intermediates were re-evaluated by ab initio methods and the mechanism was updated according to recent results. The modeling predictions were in qualitative agreement with the experimental results for the effect of K/Cl/S on moist CO oxidation, but the degree of sulfation was strongly overpredicted for KCl. Analysis of the calculations indicates that sulfation pathways in the model involving KOSO3 contribute to the overprediction, but both the thermodynamic properties and rate constants in the model involve significant uncertainties and more work is required to resolve the discrepancy." @default.
• W4311771908 created "2022-12-28" @default.
• W4311771908 creator A5007692847 @default.
• W4311771908 creator A5027618169 @default.
• W4311771908 creator A5046919396 @default.
• W4311771908 creator A5070302393 @default.
• W4311771908 creator A5079685556 @default.
• W4311771908 creator A5084140904 @default.
• W4311771908 date "2023-03-01" @default.
• W4311771908 modified "2023-09-25" @default.
• W4311771908 title "The chemical coupling between moist CO oxidation and gas-phase potassium sulfation" @default.
• W4311771908 cites W1581787963 @default.
• W4311771908 cites W1817445719 @default.
• W4311771908 cites W1968418820 @default.
• W4311771908 cites W1972872364 @default.
• W4311771908 cites W1976932008 @default.
• W4311771908 cites W1978999283 @default.
• W4311771908 cites W1982571932 @default.
• W4311771908 cites W1995350290 @default.
• W4311771908 cites W2006305929 @default.
• W4311771908 cites W2007103119 @default.
• W4311771908 cites W2017083625 @default.
• W4311771908 cites W2030202623 @default.
• W4311771908 cites W2030275483 @default.
• W4311771908 cites W2034378277 @default.
• W4311771908 cites W2042827198 @default.
• W4311771908 cites W2044002074 @default.
• W4311771908 cites W2046647511 @default.
• W4311771908 cites W2049081082 @default.
• W4311771908 cites W2052860042 @default.
• W4311771908 cites W2062096232 @default.
• W4311771908 cites W2062924011 @default.
• W4311771908 cites W2064228876 @default.
• W4311771908 cites W2073431904 @default.
• W4311771908 cites W2073663763 @default.
• W4311771908 cites W2075711588 @default.
• W4311771908 cites W2082237764 @default.
• W4311771908 cites W2084556987 @default.
• W4311771908 cites W2089109111 @default.
• W4311771908 cites W2119147562 @default.
• W4311771908 cites W2135979566 @default.
• W4311771908 cites W2166204353 @default.
• W4311771908 cites W2300260406 @default.
• W4311771908 cites W2313275148 @default.
• W4311771908 cites W2488337840 @default.
• W4311771908 cites W2531214451 @default.
• W4311771908 cites W2554893009 @default.
• W4311771908 cites W2748202569 @default.
• W4311771908 cites W2789419182 @default.
• W4311771908 cites W2789917268 @default.
• W4311771908 cites W2974874676 @default.
• W4311771908 cites W3013795804 @default.
• W4311771908 cites W3015846020 @default.
• W4311771908 cites W3089286264 @default.
• W4311771908 cites W3146667624 @default.
• W4311771908 cites W4311757953 @default.
• W4311771908 doi "https://doi.org/10.1016/j.fuel.2022.127127" @default.
• W4311771908 hasPublicationYear "2023" @default.
• W4311771908 type Work @default.
• W4311771908 citedByCount "0" @default.
• W4311771908 crossrefType "journal-article" @default.
• W4311771908 hasAuthorship W4311771908A5007692847 @default.
• W4311771908 hasAuthorship W4311771908A5027618169 @default.
• W4311771908 hasAuthorship W4311771908A5046919396 @default.
• W4311771908 hasAuthorship W4311771908A5070302393 @default.
• W4311771908 hasAuthorship W4311771908A5079685556 @default.
• W4311771908 hasAuthorship W4311771908A5084140904 @default.
• W4311771908 hasBestOaLocation W43117719081 @default.
• W4311771908 hasConcept C113196181 @default.
• W4311771908 hasConcept C121332964 @default.
• W4311771908 hasConcept C148898269 @default.
• W4311771908 hasConcept C155138218 @default.
• W4311771908 hasConcept C178790620 @default.
• W4311771908 hasConcept C179104552 @default.
• W4311771908 hasConcept C185592680 @default.
• W4311771908 hasConcept C2781042210 @default.
• W4311771908 hasConcept C43617362 @default.
• W4311771908 hasConcept C517785266 @default.
• W4311771908 hasConcept C55493867 @default.
• W4311771908 hasConcept C62520636 @default.
• W4311771908 hasConceptScore W4311771908C113196181 @default.
• W4311771908 hasConceptScore W4311771908C121332964 @default.
• W4311771908 hasConceptScore W4311771908C148898269 @default.
• W4311771908 hasConceptScore W4311771908C155138218 @default.
• W4311771908 hasConceptScore W4311771908C178790620 @default.
• W4311771908 hasConceptScore W4311771908C179104552 @default.
• W4311771908 hasConceptScore W4311771908C185592680 @default.
• W4311771908 hasConceptScore W4311771908C2781042210 @default.
• W4311771908 hasConceptScore W4311771908C43617362 @default.
• W4311771908 hasConceptScore W4311771908C517785266 @default.
• W4311771908 hasConceptScore W4311771908C55493867 @default.
• W4311771908 hasConceptScore W4311771908C62520636 @default.
• W4311771908 hasLocation W43117719081 @default.
• W4311771908 hasLocation W43117719082 @default.
• W4311771908 hasOpenAccess W4311771908 @default.
• W4311771908 hasPrimaryLocation W43117719081 @default.
• W4311771908 hasRelatedWork W1994196954 @default.
• W4311771908 hasRelatedWork W1996664277 @default.

• next