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• W4311776404 abstract "For adsorption chillers or desiccant systems, thin film adsorbents coated on heat exchanger surfaces contribute to enhance adsorption/desorption rate of vapor, due to low thermal resistance leading to quick exothermic/endothermic heat exchange with external cooling/hot fluid. They enable to downsize adsorbent heat exchanger in systems. In the present study, a silica gel thin film synthesized on aluminum plate was proposed as a novel adsorbent. Pore structure of this new adsorbent changed during 15 months after synthesis: pore diameter enlarging and specific surface area decreasing. Upon this, the influence of time elapsed after synthesis on equilibrium adsorption of water vapor was examined under various adsorbing conditions until 22 months after synthesis. The equilibrium showed S-shape curve characteristics with respect to relative humidity, and decreased monotonously with elapsed time in wide relative humidity range, which was attributed to the pore structure change. Decreasing of equilibrium was not seen after 15 months from synthesis, that is, stabilization was attained. The equilibrium reduction in low relative humidity range was analyzed with the BET equation. Moreover, relative humidity of capillary condensation occurring was compared to the Kelvin equation. Finally, the equilibrium was formulated which reproduced well the measurements over the entire relative humidity range." @default.
• W4311776404 created "2022-12-28" @default.
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• W4311776404 date "2023-02-01" @default.
• W4311776404 modified "2023-10-11" @default.
• W4311776404 title "Influence of elapsed time on adsorption equilibrium of water vapor to silica gel film" @default.
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• W4311776404 doi "https://doi.org/10.1016/j.cherd.2022.12.014" @default.
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