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- W4311822321 abstract "The employment of nitrogen Lewis acids based on nitrenium cations has been increasingly featured in the fields of main group chemistry and catalysis. A formally reduced form of nitrenium D─cyclic triazanes E─are intriguing chemical compounds, the chemistry of which is completely unexplored. In this work, we reveal that N-H-triazanes exhibit unusual N-H bond properties; namely, they can serve as protons, hydrides, or hydrogen atom donors. This unique multimodal reactivity provides an N-cation, N-anion, or N-radical from the same species. It allowed us to isolate, for the first time, a stable naphto[1,2,3]triazinyl radical, which was fully characterized both computationally and experimentally, including its monomeric X-ray structure. Moreover, this radical can be prepared directly from the nitrenium cation by a single electron reduction (E = -0.46 V), and this process is reversible. We envision versatile uses of this radical in synthetic and materials chemistry." @default.
- W4311822321 created "2022-12-29" @default.
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- W4311822321 date "2022-12-16" @default.
- W4311822321 modified "2023-10-16" @default.
- W4311822321 title "Multimodal Reactivity of N–H Bonds in Triazanes and Isolation of a Triazinyl Radical" @default.
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- W4311822321 doi "https://doi.org/10.1021/jacs.2c11113" @default.
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- W4311822321 hasPublicationYear "2022" @default.
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