Matches in SemOpenAlex for { <https://semopenalex.org/work/W4311824776> ?p ?o ?g. }
- W4311824776 endingPage "12926" @default.
- W4311824776 startingPage "12921" @default.
- W4311824776 abstract "We report highly selective photocatalytic functionalisations of alkyl groups in aryl alkyl ethers with a range of electron-poor alkenes using an acridinium catalyst with a phosphate base and irradiation with visible light (456 nm or 390 nm). Experiments indicate that the reaction operates via direct single-electron oxidation of the arene substrate ArOCHRR' to its radical cation by the excited state organic photocatalyst; this is followed by deprotonation of the ArOC-H in the radical cation to yield the radical ArOC˙RR'. This radical then attacks the electrophile to form an intermediate alkyl radical that is reduced to complete the photocatalytic cycle. The oxidation step is selective for activated arenes (ArOR) over their non-activated counterparts and the subsequent deprotonation of the methoxy group affords the α-aryloxyalkyl radical that leads to a wide range of functionalised products in good to excellent yield." @default.
- W4311824776 created "2022-12-29" @default.
- W4311824776 creator A5011911252 @default.
- W4311824776 creator A5038338444 @default.
- W4311824776 creator A5080612908 @default.
- W4311824776 date "2022-01-01" @default.
- W4311824776 modified "2023-09-25" @default.
- W4311824776 title "Highly selective α-aryloxyalkyl C–H functionalisation of aryl alkyl ethers" @default.
- W4311824776 cites W2004244816 @default.
- W4311824776 cites W2009582757 @default.
- W4311824776 cites W2013600599 @default.
- W4311824776 cites W2046375331 @default.
- W4311824776 cites W2054039581 @default.
- W4311824776 cites W2068554467 @default.
- W4311824776 cites W2071982166 @default.
- W4311824776 cites W2077254686 @default.
- W4311824776 cites W2107294894 @default.
- W4311824776 cites W2120347191 @default.
- W4311824776 cites W2145365726 @default.
- W4311824776 cites W2181938004 @default.
- W4311824776 cites W2265362920 @default.
- W4311824776 cites W2307580311 @default.
- W4311824776 cites W2314103148 @default.
- W4311824776 cites W2319420875 @default.
- W4311824776 cites W2343326307 @default.
- W4311824776 cites W2418726947 @default.
- W4311824776 cites W2480067148 @default.
- W4311824776 cites W2488628364 @default.
- W4311824776 cites W2521754066 @default.
- W4311824776 cites W2552273631 @default.
- W4311824776 cites W2586765722 @default.
- W4311824776 cites W2593538402 @default.
- W4311824776 cites W2609760729 @default.
- W4311824776 cites W2751908136 @default.
- W4311824776 cites W2765487959 @default.
- W4311824776 cites W2771086842 @default.
- W4311824776 cites W2792182372 @default.
- W4311824776 cites W2810537452 @default.
- W4311824776 cites W2885998187 @default.
- W4311824776 cites W2889771206 @default.
- W4311824776 cites W2897531901 @default.
- W4311824776 cites W2915730695 @default.
- W4311824776 cites W2915853195 @default.
- W4311824776 cites W2921693891 @default.
- W4311824776 cites W2951554782 @default.
- W4311824776 cites W2951915725 @default.
- W4311824776 cites W2952311423 @default.
- W4311824776 cites W2966664658 @default.
- W4311824776 cites W2967572288 @default.
- W4311824776 cites W2968745277 @default.
- W4311824776 cites W3007256093 @default.
- W4311824776 cites W3022390667 @default.
- W4311824776 cites W3029470224 @default.
- W4311824776 cites W3054700329 @default.
- W4311824776 cites W3081373768 @default.
- W4311824776 cites W3089947339 @default.
- W4311824776 cites W3093472807 @default.
- W4311824776 cites W3101069745 @default.
- W4311824776 cites W3126592395 @default.
- W4311824776 cites W3130510986 @default.
- W4311824776 cites W3144223307 @default.
- W4311824776 cites W3184390680 @default.
- W4311824776 cites W3184913249 @default.
- W4311824776 cites W3204003150 @default.
- W4311824776 cites W4206934443 @default.
- W4311824776 cites W4226059777 @default.
- W4311824776 doi "https://doi.org/10.1039/d2sc04463c" @default.
- W4311824776 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36519054" @default.
- W4311824776 hasPublicationYear "2022" @default.
- W4311824776 type Work @default.
- W4311824776 citedByCount "1" @default.
- W4311824776 countsByYear W43118247762023 @default.
- W4311824776 crossrefType "journal-article" @default.
- W4311824776 hasAuthorship W4311824776A5011911252 @default.
- W4311824776 hasAuthorship W4311824776A5038338444 @default.
- W4311824776 hasAuthorship W4311824776A5080612908 @default.
- W4311824776 hasBestOaLocation W43118247761 @default.
- W4311824776 hasConcept C111368507 @default.
- W4311824776 hasConcept C118629725 @default.
- W4311824776 hasConcept C127313418 @default.
- W4311824776 hasConcept C134121241 @default.
- W4311824776 hasConcept C145148216 @default.
- W4311824776 hasConcept C155647269 @default.
- W4311824776 hasConcept C161790260 @default.
- W4311824776 hasConcept C178790620 @default.
- W4311824776 hasConcept C185592680 @default.
- W4311824776 hasConcept C191897082 @default.
- W4311824776 hasConcept C192562407 @default.
- W4311824776 hasConcept C2777289219 @default.
- W4311824776 hasConcept C2777389692 @default.
- W4311824776 hasConcept C2780263894 @default.
- W4311824776 hasConcept C2781076698 @default.
- W4311824776 hasConcept C50027330 @default.
- W4311824776 hasConcept C65165184 @default.
- W4311824776 hasConcept C75473681 @default.
- W4311824776 hasConcept C96444392 @default.
- W4311824776 hasConceptScore W4311824776C111368507 @default.
- W4311824776 hasConceptScore W4311824776C118629725 @default.