Matches in SemOpenAlex for { <https://semopenalex.org/work/W4311887673> ?p ?o ?g. }
- W4311887673 endingPage "1091" @default.
- W4311887673 startingPage "1085" @default.
- W4311887673 abstract "From the preparation of pharmaceuticals to enzymatic construction of natural products, carbocations are central to molecular synthesis. Although these reactive intermediates are engaged in stereoselective processes in nature, exerting enantiocontrol over carbocations with synthetic catalysts remains challenging. Many resonance-stabilized tricoordinated carbocations, such as iminium and oxocarbenium ions, have been applied in catalytic enantioselective reactions. However, their dicoordinated counterparts (aryl and vinyl carbocations) have not, despite their emerging utility in chemical synthesis. We report the discovery of a highly enantioselective vinyl carbocation carbon–hydrogen (C–H) insertion reaction enabled by imidodiphosphorimidate organocatalysts. Active site confinement featured in this catalyst class not only enables effective enantiocontrol but also expands the scope of vinyl cation C–H insertion chemistry, which broadens the utility of this transition metal–free C(sp 3 )–H functionalization platform." @default.
- W4311887673 created "2023-01-02" @default.
- W4311887673 creator A5002383132 @default.
- W4311887673 creator A5005862481 @default.
- W4311887673 creator A5025294240 @default.
- W4311887673 creator A5026560405 @default.
- W4311887673 creator A5036989439 @default.
- W4311887673 creator A5037694872 @default.
- W4311887673 creator A5040341109 @default.
- W4311887673 creator A5042178740 @default.
- W4311887673 creator A5080413657 @default.
- W4311887673 creator A5084383117 @default.
- W4311887673 date "2022-12-09" @default.
- W4311887673 modified "2023-10-11" @default.
- W4311887673 title "Catalytic asymmetric C–H insertion reactions of vinyl carbocations" @default.
- W4311887673 cites W1963539007 @default.
- W4311887673 cites W1965277338 @default.
- W4311887673 cites W1969360633 @default.
- W4311887673 cites W1974667766 @default.
- W4311887673 cites W1985484434 @default.
- W4311887673 cites W1987126722 @default.
- W4311887673 cites W1988091937 @default.
- W4311887673 cites W1989736310 @default.
- W4311887673 cites W1998780196 @default.
- W4311887673 cites W2005008560 @default.
- W4311887673 cites W2007673547 @default.
- W4311887673 cites W2008517160 @default.
- W4311887673 cites W2011187123 @default.
- W4311887673 cites W2013402008 @default.
- W4311887673 cites W2023271753 @default.
- W4311887673 cites W2029911926 @default.
- W4311887673 cites W2038533471 @default.
- W4311887673 cites W2045955446 @default.
- W4311887673 cites W2058848030 @default.
- W4311887673 cites W2071462961 @default.
- W4311887673 cites W2076047817 @default.
- W4311887673 cites W2085752975 @default.
- W4311887673 cites W2092157292 @default.
- W4311887673 cites W2095911152 @default.
- W4311887673 cites W2096747776 @default.
- W4311887673 cites W2112850441 @default.
- W4311887673 cites W2116162937 @default.
- W4311887673 cites W2124495601 @default.
- W4311887673 cites W2127925574 @default.
- W4311887673 cites W2132525235 @default.
- W4311887673 cites W2148066840 @default.
- W4311887673 cites W2148284063 @default.
- W4311887673 cites W2149174093 @default.
- W4311887673 cites W2150697053 @default.
- W4311887673 cites W2156115804 @default.
- W4311887673 cites W2158974750 @default.
- W4311887673 cites W2160384778 @default.
- W4311887673 cites W2160790360 @default.
- W4311887673 cites W2177638519 @default.
- W4311887673 cites W2293212328 @default.
- W4311887673 cites W2325436879 @default.
- W4311887673 cites W2329762854 @default.
- W4311887673 cites W2337477920 @default.
- W4311887673 cites W2394549516 @default.
- W4311887673 cites W2558939872 @default.
- W4311887673 cites W2582880996 @default.
- W4311887673 cites W2603593421 @default.
- W4311887673 cites W2605801743 @default.
- W4311887673 cites W2610707110 @default.
- W4311887673 cites W2611157265 @default.
- W4311887673 cites W2734882627 @default.
- W4311887673 cites W2741253869 @default.
- W4311887673 cites W2752123500 @default.
- W4311887673 cites W2754303249 @default.
- W4311887673 cites W2780432268 @default.
- W4311887673 cites W2784432193 @default.
- W4311887673 cites W2789729342 @default.
- W4311887673 cites W2801715076 @default.
- W4311887673 cites W2883358227 @default.
- W4311887673 cites W2886680295 @default.
- W4311887673 cites W2890913378 @default.
- W4311887673 cites W2894971291 @default.
- W4311887673 cites W2895662576 @default.
- W4311887673 cites W2911997094 @default.
- W4311887673 cites W2913530958 @default.
- W4311887673 cites W2913818182 @default.
- W4311887673 cites W2917613065 @default.
- W4311887673 cites W2919098499 @default.
- W4311887673 cites W2932297636 @default.
- W4311887673 cites W2945952896 @default.
- W4311887673 cites W2949142973 @default.
- W4311887673 cites W2950708584 @default.
- W4311887673 cites W2951675978 @default.
- W4311887673 cites W2958682162 @default.
- W4311887673 cites W2980251553 @default.
- W4311887673 cites W2982564856 @default.
- W4311887673 cites W3003496363 @default.
- W4311887673 cites W3020719222 @default.
- W4311887673 cites W3046965163 @default.
- W4311887673 cites W3089515815 @default.
- W4311887673 cites W3090947888 @default.
- W4311887673 cites W3167019654 @default.
- W4311887673 cites W3182555529 @default.