Matches in SemOpenAlex for { <https://semopenalex.org/work/W4311902039> ?p ?o ?g. }
- W4311902039 endingPage "119007" @default.
- W4311902039 startingPage "119007" @default.
- W4311902039 abstract "The transfer hydrodehalogenation (THD) of halophenols is efficiently catalyzed by palladium supported on high surface area ceria (Pd/CeO2) under mild conditions (65 °C) using isopropanol (iPrOH) as hydrogen source. The reactivity of 4-halophenols (4-X-PhOH) varies in the order 4-F-PhOH > 4-Cl-PhOH > 4-Br-PhOH > > 4-I-PhOH and appears to be controlled by the desorption of halides from the catalyst surface. Kinetic analysis of the reactions and temperature programmed surface reaction (TPSR) experiments indicate that oxidative addition of C-X bonds and H-abstraction from isopropoxide compete for the same active sites on Pd. The catalyst was able to conduct the THD of various hazardous pollutants and emerging contaminants (dichlorodiphenyltrichloroethane (DDT), pentachlorophenol, pentafluorophenol and triclosan)." @default.
- W4311902039 created "2023-01-02" @default.
- W4311902039 creator A5011278300 @default.
- W4311902039 creator A5030589483 @default.
- W4311902039 creator A5033824482 @default.
- W4311902039 creator A5073390599 @default.
- W4311902039 creator A5075141603 @default.
- W4311902039 date "2023-01-01" @default.
- W4311902039 modified "2023-10-12" @default.
- W4311902039 title "Efficient transfer hydrodehalogenation of halophenols catalyzed by Pd supported on ceria" @default.
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