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- W4311928497 abstract "A palladium-catalyzed direct C-H functionalization of glycals with cycloalkenones is described and a series of C-2 functionalized glycals were synthesized efficiently with cyclic enones. The direct C-H functionalization of glycals with Pd(II) and subsequent insertion of cyclic enones via β-hydride elimination is the key to the synthesis of 2C-branched glycals. The synthetic utility of this methodology for chiral phenanthrenones has also been demonstrated by coupling the synthesized 2C-branched glycals with arynes via 4+2 cycloaddition followed by concomitant pyran ring opening." @default.
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- W4311928497 date "2023-01-01" @default.
- W4311928497 modified "2023-10-14" @default.
- W4311928497 title "Pd-catalyzed direct functionalization of glycals with cycloalkenones: application to the synthesis of chiral phenanthrenones" @default.
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- W4311928497 doi "https://doi.org/10.1039/d2cc05255e" @default.
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