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• W4312019601 abstract "A novel alkynyl-stabilized silver-copper alloy nanocluster with the composition of [Ag13-xCu6+x(tBuC6H4CC)14(PPh3)6](SbF6)3 was prepared by the (PPh3)2CuBH4-mediated reduction approach. The nanocluster features a centred disordered-octahedral Ag7Cu6 kernel, which is protected by hybrid alkynyl and triphenylphosphine ligands. Structural comparison of this two-electron nanocluster with other alkynyl-capped Ag/Cu ones suggested that the structure of alkynyl ligands played an important role in dictating the structures of the resulting nanoclusters. The title cluster showed high performance in the catalytic hydrogenation of 4-nitrophenol, indicative of the bright future of cluster-based catalysts." @default.
• W4312019601 created "2023-01-03" @default.
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• W4312019601 date "2023-01-01" @default.
• W4312019601 modified "2023-10-14" @default.
• W4312019601 title "An alkynyl-protected Ag_{13−<i>x</i>}Cu_6+<i>x</i> nanocluster for catalytic hydrogenation" @default.
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• W4312019601 doi "https://doi.org/10.1039/d2dt03295c" @default.
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• W4312019601 hasPublicationYear "2023" @default.
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