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• W4312035706 abstract "The catalytic hydroarylation of alkynes has emerged as an excellent methodology for the synthesis of functionalized alkenes with excellent levels of regio- and stereocontrol (syn). However, in spite of the great progress in this field, the number of asymmetric methodologies is still scarce. Herein, we report an atroposelective Ir-catalyzed C–H hydroarylation of alkynes, which enables the asymmetric synthesis of axially chiral heterobiaryl trisubstituted olefins in good to high yields and enantioselectivities up to 98% ee." @default.
• W4312035706 created "2023-01-04" @default.
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• W4312035706 date "2022-12-09" @default.
• W4312035706 modified "2023-10-16" @default.
• W4312035706 title "Ir-Catalyzed Asymmetric Hydroarylation of Alkynes for the Synthesis of Axially Chiral Heterobiaryls" @default.
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• W4312035706 doi "https://doi.org/10.1021/acscatal.2c04524" @default.
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