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- W4312067095 endingPage "2205619" @default.
- W4312067095 startingPage "2205619" @default.
- W4312067095 abstract "Metal-organic frameworks (MOF) have attracted extensive attention due to their ultra-high specific surface area and tunable structure, the mechanism of direct utilization for capacitive deionization (CDI) defluorination remains undefined. Here, MIL-101(Cr) with ultra-high specific surface area, high water stability, and open metal sites (OMSs) is prepared by a hydrothermal method for defluorination of CDI. Carbon black is used as a chain to connect F-stored in the holes of MIL-101(Cr) (Cr-MOF)as blocks to enhance the conductivity and ion storage capacity of MIL-101(Cr)/carbon black electrodes (Cr-MOF electrodes). This simple construction method avoids the process complexity of in situ synthesis and performs better. These easily constructed blockchain-like Cr-MOF electrodes exhibit excellent defluorination capacity (39.84 mgNaF gelectrodes-1 ), low energy consumption (1.2 kWh kgNaF-1 ), and good stability. The coupling of the electrochemical redox reaction of Cr3+ /Cr4+ with confined water is investigated using in situ and ex situ analysis methods combined with density functional theory (DFT), resulting in an unprecedented defluorination mechanism for Cr-MOF electrodes. This study opens up new ideas for the application of MOF in CDI, clarifies the removal mechanism of MOF, and lays a foundation for further promoting the application of raw materials with poor conductivity in the field of CDI." @default.
- W4312067095 created "2023-01-04" @default.
- W4312067095 creator A5016919017 @default.
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- W4312067095 creator A5085352082 @default.
- W4312067095 creator A5088406552 @default.
- W4312067095 date "2022-12-20" @default.
- W4312067095 modified "2023-10-09" @default.
- W4312067095 title "“Blockchain‐Like” MIL‐101(Cr)/Carbon Black Electrodes for Unprecedented Defluorination by Capacitive Deionization" @default.
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- W4312067095 doi "https://doi.org/10.1002/smll.202205619" @default.
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- W4312067095 hasPublicationYear "2022" @default.
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