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- W4312093623 abstract "A Lewis acid mediated conjugate addition of isocyanides to β-hydroxy-α-diazo carbonyls has been developed for the first time. The reaction realizes the efficient construction of quaternary carbon centers and provides a novel and efficient strategy for the synthesis of β-carboxamido-α-diazo carbonyls that would be otherwise difficult to form in a single step. Further applications, including synthesis of methylenecyclohexane, spiro-β-lactam, and nitrogen-bridged tricyclic β-lactam, demonstrated the tremendous potential of the coupling reaction." @default.
- W4312093623 created "2023-01-04" @default.
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- W4312093623 date "2022-12-22" @default.
- W4312093623 modified "2023-10-13" @default.
- W4312093623 title "Lewis Acid Mediated Conjugate Addition of Isocyanides to β-Hydroxy-α-diazo Carbonyls: Synthesis of β-Carboxamido-α-diazo Carbonyl Compounds" @default.
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- W4312093623 doi "https://doi.org/10.1021/acs.orglett.2c04050" @default.
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