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- W4312094900 abstract "The localized surface-plasmon resonance of metal nanoparticles and clusters corresponds to a collective charge oscillation of the quasi-free metal electrons. The polarization of the more localized d electrons opposes the overall polarization of the electron cloud and thus screens the surface plasmon. By contrast, a static electric external field is well screened, as even very small noble-metal clusters are highly metallic: the field inside is practically zero except for the effect of the Friedel-oscillation-like modulations which lead to small values of the polarization of the d electrons. In the present article, we present and compare representations of the induced densities (i) connected to the surface-plasmon resonance and (ii) resulting from an external static electric field. The two cases allow for an intuitive understanding of the differences between the dynamic and the static screening." @default.
- W4312094900 created "2023-01-04" @default.
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- W4312094900 date "2023-01-01" @default.
- W4312094900 modified "2023-10-17" @default.
- W4312094900 title "Visualizing screening in noble-metal clusters: static <i>vs.</i> dynamic" @default.
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- W4312094900 doi "https://doi.org/10.1039/d2cp04316e" @default.
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