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- W4312143600 abstract "We combined the advantages of the 2-methylimidazole zinc salt (ZIF-8) and hydroxylated boron nitride (OH-BN) materials to prepare a new bifunctional separation material, namely ZIF-BN. In this, spherical ZIF-8 materials fill the macroporous structure of OH-BN sheets by coordination bonds due to the edge effect. Furthermore, a series of ZIF-BN/PVA membranes were prepared using the vacuum-assisted filtration of the layer-by-layer for the gas separation study. The trace amounts of PVA connect adjacent ZIF-BN sheets through hydrogen bonds, without covering the pore structures of ZIF-8 materials. Based on this exclusive strategy for preparing membranes, the obtained membranes exhibit superior H2 separation performances. Compared with the pure PVA membrane, the H2 permeability, H2/CO2 selectivity, and H2/N2 selectivity of the ZIF-BN/PVA-8 membrane have increased (54, 13, & 12)-fold, to (600 Barrer, 97.2, & 173.6), respectively. This strategy provides a facile way to design new bifunctional membranes for gas separation applications." @default.
- W4312143600 created "2023-01-04" @default.
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- W4312143600 date "2023-02-01" @default.
- W4312143600 modified "2023-10-18" @default.
- W4312143600 title "Poly(vinyl alcohol) mediated bifunctional ZIF-BN nanocomposite for the high-selectivity H2 separation membrane" @default.
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- W4312143600 doi "https://doi.org/10.1016/j.compositesb.2022.110488" @default.
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