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- W4312155280 endingPage "9310" @default.
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- W4312155280 abstract "An efficient two-step method for synthesizing 2-(trifluoromethyl)- and 2-(difluoromethyl)benzoheteroles bearing various substituents was developed. Commercially available HFO-1224yd(Z) or HFO-1233yd(Z) underwent the Suzuki-Miyaura coupling with arylboronic acids (acid esters) bearing a nucleophilic moiety at the ortho position to yield the corresponding β-fluoro-β-(trifluoromethyl)- or β-fluoro-β-(difluoromethyl)styrenes, respectively. Treatment of the obtained styrenes with potassium phosphate induced nucleophilic 5-endo-trig cyclization to provide the corresponding 2-trifluoromethylated or 2-difluoromethylated indoles and benzofurans, as well as benzothiophenes." @default.
- W4312155280 created "2023-01-04" @default.
- W4312155280 creator A5030722990 @default.
- W4312155280 creator A5039413454 @default.
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- W4312155280 date "2022-12-12" @default.
- W4312155280 modified "2023-10-13" @default.
- W4312155280 title "Two-Step Synthesis of 2-Trifluoromethylated and 2-Difluoromethylated Benzoheteroles Starting from HFO-1224yd(<i>Z</i>) and HFO-1233yd(<i>Z</i>)" @default.
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- W4312155280 doi "https://doi.org/10.1021/acs.orglett.2c03930" @default.
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