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- W4312174606 abstract "Coal is a carrier of carbon enrichment, so it has the potential for the preparation of coal-based carbon materials. In this paper, LT anthracite and TSG bituminous coal were selected, and the corresponding graphitized samples were prepared from high-temperature treatment. The effects of silicon-containing minerals on coal evolution during the high-temperature pre-graphitization stage were investigated by XRD, Raman spectroscopy, and SEM. The results showed that with increasing temperature, the silicon-containing samples showed smaller d002 and ID1/IG, and higher Lc, while La presented a slight increase. It was found by SEM that the micromorphology of all samples was mainly massive structures. Meanwhile, irregular polyhedral structures also were observed in silicon-containing samples at 1300 °C, which were related to the formation and deposition of SiC. The carbothermal reactions of silicon-containing minerals continued to generate SiC and precipitate with increasing temperature, resulting in the gradual transformation of the needle-like structures into polyhedral structures. However, SiC was completely decomposed at 2800 °C. These changes indicated that during the pre-graphitization stage, silicon-containing minerals form SiC to advance the reduction of the interlayer spacing and the increase of longitudinal layer stacking height, thereby enhancing structural ordering and graphitization degree, while it had less effect on the lateral size. This will help to further understand the role of silicon-containing minerals in the coal pre-graphitization stage and also provide useful information about synthetic coal-based graphite." @default.
- W4312174606 created "2023-01-04" @default.
- W4312174606 creator A5029579688 @default.
- W4312174606 creator A5046253614 @default.
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- W4312174606 date "2022-12-23" @default.
- W4312174606 modified "2023-10-06" @default.
- W4312174606 title "The Effect of Silicon-Containing Minerals on Coal Evolution at High-Temperature Pre-Graphitization Stage" @default.
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- W4312174606 doi "https://doi.org/10.3390/min13010020" @default.
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