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- W4312178897 abstract "The dynamic covalent chemistry of molecular disulfides has been studied extensively in solution, but their reactivity when confined to nanospaces has not been investigated, nor has their application to functional nanomaterials been explored. In this study, symmetrical organic disulfides were tethered to the basal planes of synthetic mica by intercalation, confining photo-induced reactions to the interlayer as a result. This approach functionalizes the nanosheets to act as host for photo-induced disulfide-disulfide, disulfide-thiol, and disulfide-ene reactions, providing control and versatility for a wide variety of applications. Symmetrical organic disulfides were tethered to the basal planes of synthetic mica by intercalation, confining photo-induced reactions to the interlayer as a result. This approach functionalizes the nanosheets to act as host for photo-induced disulfide-disulfide, disulfide-thiol, and disulfide-ene reactions, providing control and versatility for a wide variety of applications." @default.
- W4312178897 created "2023-01-04" @default.
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- W4312178897 date "2023-01-15" @default.
- W4312178897 modified "2023-09-27" @default.
- W4312178897 title "Tethering Organic Disulfides to Layered Silicates: A Versatile Strategy for Photo-Controllable Dynamic Chemistry and Functionalization" @default.
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- W4312178897 doi "https://doi.org/10.1246/bcsj.20220309" @default.
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