Matches in SemOpenAlex for { <https://semopenalex.org/work/W4312184304> ?p ?o ?g. }
- W4312184304 abstract "Abstract Using solar energy through green and simple artificial photosynthesis systems are considered as a promising way to solve the energy and environmental crisis. However, one of the important primary steps of photosynthesis, i.e., energy transfer, is long being ignored especially in inorganic semiconducting systems due to the small exciton binding energies. Herein, the simultaneous interrogation of the charge transfer and energy transfer steps in a photoexcitation process is proposed by utilizing few‐layered nanosheet‐assembled hierarchical BiOBr nanotubes with rich oxygen vacancies (OVs) as efficient multifunctional photocatalysts. Benefiting from the integrated 1D/2D structure and abundant OV defects, the excitonic effect strikes a delicate balance in the optimized BiOBr photocatalyst, showing not only improved charge carrier separation and transfer but also enhanced exciton generation. As a result, the hierarchical BiOBr nanotubes exhibit high efficiency toward photocatalytic CO 2 reduction with an impressive CO evolution rate of 135.6 µmol g −1 h −1 without cocatalyst or photosensitizer. The dominant reactive oxygen species of singlet oxygen ( 1 O 2 ) are discriminated for the first time, which originated from an energy transfer process, with electrophilic character, whereas the minor effect of superoxide anion radical ( • O 2 − ) with a nucleophilic rate‐determining step in the photocatalytic aerobic oxidation of sulfides." @default.
- W4312184304 created "2023-01-04" @default.
- W4312184304 creator A5021523686 @default.
- W4312184304 creator A5026410124 @default.
- W4312184304 creator A5052351967 @default.
- W4312184304 creator A5075636506 @default.
- W4312184304 date "2022-12-22" @default.
- W4312184304 modified "2023-10-14" @default.
- W4312184304 title "Oxygen Vacancy‐Mediated Exciton Effect in Hierarchical BiOBr Enables Dichotomy of Energy Transfer and Electron Transfer in Photocatalysis" @default.
- W4312184304 cites W1979060873 @default.
- W4312184304 cites W1997572663 @default.
- W4312184304 cites W2030170783 @default.
- W4312184304 cites W2039475650 @default.
- W4312184304 cites W2065010446 @default.
- W4312184304 cites W2074620795 @default.
- W4312184304 cites W2100903105 @default.
- W4312184304 cites W2118572129 @default.
- W4312184304 cites W2127393068 @default.
- W4312184304 cites W2144664554 @default.
- W4312184304 cites W2164558411 @default.
- W4312184304 cites W2282747961 @default.
- W4312184304 cites W2293692914 @default.
- W4312184304 cites W2332308363 @default.
- W4312184304 cites W2342670435 @default.
- W4312184304 cites W2548735727 @default.
- W4312184304 cites W2588805918 @default.
- W4312184304 cites W2594543377 @default.
- W4312184304 cites W2604829804 @default.
- W4312184304 cites W2744078894 @default.
- W4312184304 cites W2764082644 @default.
- W4312184304 cites W2768038472 @default.
- W4312184304 cites W2783646620 @default.
- W4312184304 cites W2794692883 @default.
- W4312184304 cites W2797346725 @default.
- W4312184304 cites W2800772908 @default.
- W4312184304 cites W2802790156 @default.
- W4312184304 cites W2804218069 @default.
- W4312184304 cites W2883558793 @default.
- W4312184304 cites W2889795902 @default.
- W4312184304 cites W2899684319 @default.
- W4312184304 cites W2911342135 @default.
- W4312184304 cites W2941394241 @default.
- W4312184304 cites W2955662668 @default.
- W4312184304 cites W2962552052 @default.
- W4312184304 cites W2964457289 @default.
- W4312184304 cites W2966222655 @default.
- W4312184304 cites W2977774099 @default.
- W4312184304 cites W2999286052 @default.
- W4312184304 cites W3013265070 @default.
- W4312184304 cites W3022417726 @default.
- W4312184304 cites W3022457912 @default.
- W4312184304 cites W3024260233 @default.
- W4312184304 cites W3031190707 @default.
- W4312184304 cites W3043891944 @default.
- W4312184304 cites W3047272953 @default.
- W4312184304 cites W3082585248 @default.
- W4312184304 cites W3114812336 @default.
- W4312184304 cites W3127207240 @default.
- W4312184304 cites W3133534375 @default.
- W4312184304 cites W3172063618 @default.
- W4312184304 cites W3184408270 @default.
- W4312184304 cites W3200112708 @default.
- W4312184304 cites W3203614705 @default.
- W4312184304 cites W3205045304 @default.
- W4312184304 cites W3215075364 @default.
- W4312184304 cites W4214908848 @default.
- W4312184304 cites W4226228181 @default.
- W4312184304 cites W4238123645 @default.
- W4312184304 cites W4289526197 @default.
- W4312184304 cites W4361868665 @default.
- W4312184304 doi "https://doi.org/10.1002/adfm.202213935" @default.
- W4312184304 hasPublicationYear "2022" @default.
- W4312184304 type Work @default.
- W4312184304 citedByCount "7" @default.
- W4312184304 countsByYear W43121843042023 @default.
- W4312184304 crossrefType "journal-article" @default.
- W4312184304 hasAuthorship W4312184304A5021523686 @default.
- W4312184304 hasAuthorship W4312184304A5026410124 @default.
- W4312184304 hasAuthorship W4312184304A5052351967 @default.
- W4312184304 hasAuthorship W4312184304A5075636506 @default.
- W4312184304 hasConcept C121332964 @default.
- W4312184304 hasConcept C123669783 @default.
- W4312184304 hasConcept C135473242 @default.
- W4312184304 hasConcept C147789679 @default.
- W4312184304 hasConcept C155220765 @default.
- W4312184304 hasConcept C159467904 @default.
- W4312184304 hasConcept C161790260 @default.
- W4312184304 hasConcept C171250308 @default.
- W4312184304 hasConcept C17525397 @default.
- W4312184304 hasConcept C17729963 @default.
- W4312184304 hasConcept C178790620 @default.
- W4312184304 hasConcept C181500209 @default.
- W4312184304 hasConcept C184779094 @default.
- W4312184304 hasConcept C185592680 @default.
- W4312184304 hasConcept C192562407 @default.
- W4312184304 hasConcept C2777516457 @default.
- W4312184304 hasConcept C51967427 @default.
- W4312184304 hasConcept C52859227 @default.
- W4312184304 hasConcept C540031477 @default.
- W4312184304 hasConcept C62520636 @default.