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- W4312203690 abstract "A novel strategy was proposed to scrub NOx pollutant originated from sintering flue gases by oxidation combined with wet flue gas denitrification technology. CuCl2 that could be adopted repeatedly was introduced as an additive into the sulfite solution to enhance NO2 removal. Comparing with the sulfite solution (0.05 mol/L), the absorption efficiency improved from 75% to 100%, and the stabilization period extended from 10 to 40 min notably with the addition of CuCl2. The intensification by CuCl2 addition was related to the formation of CuCl during the reaction of CuCl2 and SO32−, which was found to be more effective in removing NO2. Afterwards, CuCl transformed to Cu2+ substance again and this mutual transformation between CuCl and Cu2+ substance indicated a cyclic use of CuCl2 additive. Moreover, the feasible reaction pathway was further proved by DFT calculations. Additionally, the investigation on NO2 absorption at various operating parameters provided theoretical support for the practical application of CuCl2 in denitrification." @default.
- W4312203690 created "2023-01-04" @default.
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- W4312203690 date "2023-03-01" @default.
- W4312203690 modified "2023-10-16" @default.
- W4312203690 title "Intensification of NO2 removal in sulfite solutions with reusable copper chloride: Mechanism and process parameters" @default.
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- W4312203690 doi "https://doi.org/10.1016/j.seppur.2022.122996" @default.
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