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- W4312214046 abstract "The peroxymonocarbonate anion, HCO4-, the covalent adduct between the carbon dioxide and hydrogen peroxide anion, effectively reacts with SO2 in the gas phase following three oxidative routes. Mass spectrometric and electronic structure calculations show that sulphur dioxide is oxidised through a common intermediate to the hydrogen sulphate anion, sulphur trioxide, and sulphur trioxide anion as primary products through formal HO2-, oxygen atom, and oxygen ion transfers. The hydrogen sulphite anion is also formed as a secondary product from the oxygen atom transfer path. The uncommon nucleophilic behaviour of HCO4- is disclosed by the Lewis acidic properties of SO2, an amphiphilic molecule that forms intermediates with characteristic and diagnostic geometries with peroxymonocarbonate." @default.
- W4312214046 created "2023-01-04" @default.
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- W4312214046 date "2022-12-23" @default.
- W4312214046 modified "2023-09-26" @default.
- W4312214046 title "The Peroxymonocarbonate Anion HCO4− as an Effective Oxidant in the Gas Phase: A Mass Spectrometric and Theoretical Study on the Reaction with SO2" @default.
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- W4312214046 doi "https://doi.org/10.3390/molecules28010132" @default.
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