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- W4312470936 abstract "Formaldehyde-free adhesive based on oxidized starch (OS) adhesives was formulated at different crosslinkers types and contents to replace urea–formaldehyde (UF) resins for plywood. Different types of crosslinker, i.e., blocked-pMDI (B-pMDI) and citric acid (CA), and levels of the crosslinkers (5.0, 7.5, 10%) were employed to tailor the adhesion performance of OS adhesives with H2O2/starch mole ratio of 0.5. Technological properties of OS adhesives such as primary properties, chemical and thermal properties were characterized using several methods. Adhesion performance of OS was evaluated in plywood panel according to the Japanese Agricultural Standard (JAS) 233:2003. FTIR spectroscopy revealed that the amide linkages were formed by reacting the OS with B-pMDI, and ester linkages were built by reacting OS with CA. These two linkages governed the adhesion performance of OS in plywood. OS/BpMDI adhesive generally had higher curing temperature values than the OS/CA. Moreover, greater content of the crosslinker accelerated the curing reaction. Tensile shear strength of plywood increased with higher crosslinker content from 0.61 MPa to 1.35 MPa, showing that crosslinker had a significant effect on enhancing the adhesion performance of OS adhesive by increasing crosslinking density and forming bigger network than without addition of crosslinker. Plywood bonded with OS/B-pMDI adhesive exhibited better adhesion than that of OS/CA bonded panel and without formaldehyde emission. Adding 10% crosslinker into OS resulted in plywood comparable to the UF bonded panel. This study suggested that OS adhesives mixed with B-pMDI can be used to produce plywood in the future." @default.
- W4312470936 created "2023-01-04" @default.
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- W4312470936 date "2022-01-01" @default.
- W4312470936 modified "2023-09-27" @default.
- W4312470936 title "Technological Properties of Formaldehyde Free Adhesives Based on Oxidized Starch Mixed with Different Crosslinkers for Plywood" @default.
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- W4312470936 doi "https://doi.org/10.1007/978-981-19-0308-3_4" @default.
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