Matches in SemOpenAlex for { <https://semopenalex.org/work/W4312694328> ?p ?o ?g. }
Showing items 1 to 71 of
71
with 100 items per page.
- W4312694328 endingPage "20" @default.
- W4312694328 startingPage "20" @default.
- W4312694328 abstract "Owing to the intrinsic complexity of crystallization and the heterogeneity of precursors, the specific stages and corresponding behaviors of an actual crystallization system remain ambiguous, which makes the univariate-controlled crystallization-kinetics-regulated synthesis and design of zeolite morphology and porosity an unrealized blueprint. In this study, a facile and univariate modulation (i.e., OH-/SiO2) strategy was developed to regulate zeolite crystallization kinetics, and zeolite L mesocrystals were synthesized rapidly (within 1-2 h) with almost all LTL morphologies (from cylindrical or disc-like shapes to nanoclusters or nanocrystals) in the simplest SiO2-Al2O3-K2O-H2O system. Using time-resolved analysis of the change in the solid-liquid Si/Al nutrient and crystallinity evolution, the intertwined and complex crystallization processes of zeolite L were clearly distinguished into four distinct stages: induction, nucleation, growth, and ripening. Under alkalinity-controlled conditions, the reactivity, Si/Al distribution, and state of aluminosilicates were critical to the formation of short-range order in the amorphous matrix, which greatly influenced the nucleation frequency and assembly state. Subsequently, these nucleation differences evoked correspondingly different kinetic growth behaviors. A putative alkalinity-controlled nonclassical crystallization mechanism was uncovered, and its validity was evaluated by analyzing morphology evolution, NH4F etching, and the effects of modifiers. Furthermore, adsorption tests demonstrated the high adsorption capacity of a series of zeolite L for guest molecules with various sizes and properties (e.g., gaseous aromatic hydrocarbon, aqueous dye, and protein)." @default.
- W4312694328 created "2023-01-05" @default.
- W4312694328 date "2022-01-01" @default.
- W4312694328 modified "2023-09-30" @default.
- W4312694328 title "Alkalinity-controlled zeolite nucleation and growth: ultrafast synthesis of total-morphology zeolite L mesocrystals and adsorption evaluation" @default.
- W4312694328 doi "https://doi.org/10.20517/cs.2022.25" @default.
- W4312694328 hasPublicationYear "2022" @default.
- W4312694328 type Work @default.
- W4312694328 citedByCount "0" @default.
- W4312694328 crossrefType "journal-article" @default.
- W4312694328 hasBestOaLocation W43126943281 @default.
- W4312694328 hasConcept C105281773 @default.
- W4312694328 hasConcept C127413603 @default.
- W4312694328 hasConcept C150394285 @default.
- W4312694328 hasConcept C161790260 @default.
- W4312694328 hasConcept C171250308 @default.
- W4312694328 hasConcept C175854130 @default.
- W4312694328 hasConcept C178790620 @default.
- W4312694328 hasConcept C185592680 @default.
- W4312694328 hasConcept C192562407 @default.
- W4312694328 hasConcept C203036418 @default.
- W4312694328 hasConcept C26456737 @default.
- W4312694328 hasConcept C2778077586 @default.
- W4312694328 hasConcept C2778402822 @default.
- W4312694328 hasConcept C42360764 @default.
- W4312694328 hasConcept C45812177 @default.
- W4312694328 hasConcept C46275449 @default.
- W4312694328 hasConcept C56052488 @default.
- W4312694328 hasConcept C61048295 @default.
- W4312694328 hasConcept C8010536 @default.
- W4312694328 hasConcept C85704489 @default.
- W4312694328 hasConceptScore W4312694328C105281773 @default.
- W4312694328 hasConceptScore W4312694328C127413603 @default.
- W4312694328 hasConceptScore W4312694328C150394285 @default.
- W4312694328 hasConceptScore W4312694328C161790260 @default.
- W4312694328 hasConceptScore W4312694328C171250308 @default.
- W4312694328 hasConceptScore W4312694328C175854130 @default.
- W4312694328 hasConceptScore W4312694328C178790620 @default.
- W4312694328 hasConceptScore W4312694328C185592680 @default.
- W4312694328 hasConceptScore W4312694328C192562407 @default.
- W4312694328 hasConceptScore W4312694328C203036418 @default.
- W4312694328 hasConceptScore W4312694328C26456737 @default.
- W4312694328 hasConceptScore W4312694328C2778077586 @default.
- W4312694328 hasConceptScore W4312694328C2778402822 @default.
- W4312694328 hasConceptScore W4312694328C42360764 @default.
- W4312694328 hasConceptScore W4312694328C45812177 @default.
- W4312694328 hasConceptScore W4312694328C46275449 @default.
- W4312694328 hasConceptScore W4312694328C56052488 @default.
- W4312694328 hasConceptScore W4312694328C61048295 @default.
- W4312694328 hasConceptScore W4312694328C8010536 @default.
- W4312694328 hasConceptScore W4312694328C85704489 @default.
- W4312694328 hasIssue "4" @default.
- W4312694328 hasLocation W43126943281 @default.
- W4312694328 hasOpenAccess W4312694328 @default.
- W4312694328 hasPrimaryLocation W43126943281 @default.
- W4312694328 hasRelatedWork W1504772604 @default.
- W4312694328 hasRelatedWork W196935166 @default.
- W4312694328 hasRelatedWork W1984256059 @default.
- W4312694328 hasRelatedWork W2049560409 @default.
- W4312694328 hasRelatedWork W2083131731 @default.
- W4312694328 hasRelatedWork W2356986807 @default.
- W4312694328 hasRelatedWork W2379651308 @default.
- W4312694328 hasRelatedWork W2541726290 @default.
- W4312694328 hasRelatedWork W3123656443 @default.
- W4312694328 hasRelatedWork W4322753357 @default.
- W4312694328 hasVolume "2" @default.
- W4312694328 isParatext "false" @default.
- W4312694328 isRetracted "false" @default.
- W4312694328 workType "article" @default.