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- W4313149849 abstract "Abstract After its discovery in 1938 the hydroformylation reaction soon became the most successful example for a homogeneously catalyzed industrial process, with an estimated installed annual capacity of almost 8 million tons in 2000. After the first plant start‐up in 1942, several companies developed cobalt‐based high pressure oxo processes. Shell and others developed high pressure processes with unmodified rhodium catalysts during the mid‐sixties. The introduction of ligand‐modified rhodium catalysts in 1976 allowed for smoother reaction conditions (pressure and temperature) and better selectivities toward linear products. Further milestones include usage of water‐soluble (Ruhrchemie/Rhone‐Poulenc Process, 1984) and phosphite‐modified rhodium catalysts (Union Carbide Mark IV, 1995). Both processes have their advantages in the catalyst/product separation (RCH/RP) or the improved yield of linear products (UCC Mark IV). All processes are discussed in depth in the article." @default.
- W4313149849 created "2023-01-06" @default.
- W4313149849 creator A5059169047 @default.
- W4313149849 date "2002-12-13" @default.
- W4313149849 modified "2023-10-12" @default.
- W4313149849 title "Hydroformylation – Industrial" @default.
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- W4313149849 doi "https://doi.org/10.1002/0471227617.eoc110" @default.
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