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• W4313197705 endingPage "2205578" @default.
• W4313197705 startingPage "2205578" @default.
• W4313197705 abstract "The construction of transparent ceramics under mild conditionsand standard atmospheric pressure has great scientific and technological potential; however, it remains difficult to achieve when conventional ceramic sintering techniques are used. Herein, a mild strategy for constructing dual-phase optical ceramics with high crystallinity (>90%) based on the stepped dual-phase crystallization of hybridized aluminosilicate glass is presented. Theoretical and experimental studies reveal that the hybridization of the glass system enables a new balance between the glass-forming ability and crystallization and can overcome the uncontrolled devitrification phenomenon during the dense crystallization of glass. Transparent hybridized oxide-fluoride ceramics with fiber geometry and dual-phase microstructures are also successfully fabricated. The generality of the strategy is confirmed, and transparent ceramics with various chemical compositions and phase combinations are prepared. Additionally, the cross-section of the ceramic fibers can be easily tuned into a circle, square, trapezoid, or even a triangle. Furthermore, the practical applications of optical ceramics for lighting and X-ray imaging are demonstrated. The findings described here suggest a major step toward expanding the scope of optical ceramics." @default.
• W4313197705 created "2023-01-06" @default.
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• W4313197705 date "2023-02-05" @default.
• W4313197705 modified "2023-10-02" @default.
• W4313197705 title "Hybridization Engineering of Oxyfluoride Aluminosilicate Glass for Construction of Dual‐Phase Optical Ceramics" @default.
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• W4313197705 doi "https://doi.org/10.1002/adma.202205578" @default.
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