Matches in SemOpenAlex for { <https://semopenalex.org/work/W4313200864> ?p ?o ?g. }
- W4313200864 endingPage "112873" @default.
- W4313200864 startingPage "112873" @default.
- W4313200864 abstract "Molybdenum trioxide doped on fibrous silica-titania (MoO3/FST) has been synthesized and evaluated in the catalytic isomerization of C5–C7 for the first time. The structure characterization, functional group, and acid distribution of MoO3/FST were assessed via XRD, N2-physisorption, FTIR, and Py-IR analysis. The IR spectra revealed that MoO3/FST was occupied by a moderate-to-strong Brønsted and Lewis acid sites distribution. By adding MoO3, intense metal-support interactions were formed, lessening Brønsted acid sites' intensity in contrast to the increasing Lewis acid sites' intensity. The isomerization test demonstrated that maximum conversions of 50.0, 80.0, and 84.0% were acquired at 300 °C corresponding to n-C5, n-C6, and n-C7, respectively. As the isomerization temperature rose from 150 to 350 °C, the yield of n-C5 to n-C7 isomers increased to ∼70.0%. The high activity of MoO3/FST was ascribed to the effective interaction between MoO3 with perturbed silanol groups, which led to enrichment in protonic acid site formation via H2 spillover. This finding proves that the isomerization catalysts should possess great Lewis acid and Bronsted acid sites to enrich the protonic acid side, resulting in high performance in isomerization." @default.
- W4313200864 created "2023-01-06" @default.
- W4313200864 creator A5019387139 @default.
- W4313200864 creator A5022181476 @default.
- W4313200864 creator A5024559085 @default.
- W4313200864 creator A5025761481 @default.
- W4313200864 creator A5041777095 @default.
- W4313200864 creator A5050203898 @default.
- W4313200864 creator A5050969469 @default.
- W4313200864 creator A5068544827 @default.
- W4313200864 creator A5077330100 @default.
- W4313200864 creator A5080252302 @default.
- W4313200864 creator A5083035039 @default.
- W4313200864 date "2023-01-01" @default.
- W4313200864 modified "2023-09-30" @default.
- W4313200864 title "New insight into the mechanism of isomerization of C5–C7 alkanes over MoO3/FST" @default.
- W4313200864 cites W1217324157 @default.
- W4313200864 cites W1976630742 @default.
- W4313200864 cites W1982554447 @default.
- W4313200864 cites W1988911911 @default.
- W4313200864 cites W1990602085 @default.
- W4313200864 cites W1999586398 @default.
- W4313200864 cites W2000009737 @default.
- W4313200864 cites W2004372604 @default.
- W4313200864 cites W2007938668 @default.
- W4313200864 cites W2009771978 @default.
- W4313200864 cites W2009971723 @default.
- W4313200864 cites W2018760012 @default.
- W4313200864 cites W2021260225 @default.
- W4313200864 cites W2021601679 @default.
- W4313200864 cites W2021907569 @default.
- W4313200864 cites W2028583638 @default.
- W4313200864 cites W2039222184 @default.
- W4313200864 cites W2043091303 @default.
- W4313200864 cites W2045886817 @default.
- W4313200864 cites W2050436109 @default.
- W4313200864 cites W2056704484 @default.
- W4313200864 cites W2060094567 @default.
- W4313200864 cites W2064652643 @default.
- W4313200864 cites W2065127324 @default.
- W4313200864 cites W2069165650 @default.
- W4313200864 cites W2072961528 @default.
- W4313200864 cites W2077857757 @default.
- W4313200864 cites W2078897733 @default.
- W4313200864 cites W2083441672 @default.
- W4313200864 cites W2172252362 @default.
- W4313200864 cites W2249264421 @default.
- W4313200864 cites W2283422578 @default.
- W4313200864 cites W2285097324 @default.
- W4313200864 cites W2478449641 @default.
- W4313200864 cites W2494028128 @default.
- W4313200864 cites W2521505074 @default.
- W4313200864 cites W2566248217 @default.
- W4313200864 cites W2594780605 @default.
- W4313200864 cites W2790831919 @default.
- W4313200864 cites W2791917830 @default.
- W4313200864 cites W2793178742 @default.
- W4313200864 cites W2793877395 @default.
- W4313200864 cites W2805929581 @default.
- W4313200864 cites W2903280657 @default.
- W4313200864 cites W2925306723 @default.
- W4313200864 cites W2939527120 @default.
- W4313200864 cites W2940839593 @default.
- W4313200864 cites W2952355467 @default.
- W4313200864 cites W2963612690 @default.
- W4313200864 cites W2968749832 @default.
- W4313200864 cites W2972363531 @default.
- W4313200864 cites W2981479507 @default.
- W4313200864 cites W3087321263 @default.
- W4313200864 cites W3087775477 @default.
- W4313200864 cites W3093261397 @default.
- W4313200864 cites W3107243560 @default.
- W4313200864 cites W3119721780 @default.
- W4313200864 cites W3131328797 @default.
- W4313200864 cites W3184499942 @default.
- W4313200864 cites W3184746956 @default.
- W4313200864 cites W4200537775 @default.
- W4313200864 cites W4205953949 @default.
- W4313200864 cites W4210689662 @default.
- W4313200864 cites W4223481848 @default.
- W4313200864 cites W4241761283 @default.
- W4313200864 cites W4280517762 @default.
- W4313200864 cites W4281988951 @default.
- W4313200864 cites W4285585263 @default.
- W4313200864 doi "https://doi.org/10.1016/j.mcat.2022.112873" @default.
- W4313200864 hasPublicationYear "2023" @default.
- W4313200864 type Work @default.
- W4313200864 citedByCount "0" @default.
- W4313200864 crossrefType "journal-article" @default.
- W4313200864 hasAuthorship W4313200864A5019387139 @default.
- W4313200864 hasAuthorship W4313200864A5022181476 @default.
- W4313200864 hasAuthorship W4313200864A5024559085 @default.
- W4313200864 hasAuthorship W4313200864A5025761481 @default.
- W4313200864 hasAuthorship W4313200864A5041777095 @default.
- W4313200864 hasAuthorship W4313200864A5050203898 @default.
- W4313200864 hasAuthorship W4313200864A5050969469 @default.
- W4313200864 hasAuthorship W4313200864A5068544827 @default.
- W4313200864 hasAuthorship W4313200864A5077330100 @default.