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- W4313200877 abstract "Metal organic frameworks (MOFs) are considered as desirable precursors for the preparation of photocatalyst to improve photocatalytic hydrogen evolution efficiency due to the maintained special morphology. Herein, C-doped rod-like ZnO with porous structure has been successfully prepared by using ZIF-L as precursor via an optimized two-step calcination strategy, which is applied for photocatalytic hydrogen evolution reaction from water splitting. The results show that ZnO-350-450 exhibits the best photocatalytic activity with a hydrogen production rate of 0.35 mmol·g−1·h−1, which is 1.9 times higher than that of ZnO-400 (0.184 mmol·g−1·h−1) under simulated sunlight illumination. The enhanced photocatalytic performance is attributed to the fact that the two-step calcination provides the regular porous rod-like structure (ZIF-L) and the inclusion of carbon in ZnO photocatalyst. C-doped ZnO with regular morphology offers faster charge transfer rate and higher charge separation efficiency, and the C-doped expands a wider range of light absorption. Overall, the presented work could provide a new idea for designing and preparing of photocatalysts with high efficiency for photocatalytic hydrogen production." @default.
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- W4313200877 date "2023-03-01" @default.
- W4313200877 modified "2023-10-06" @default.
- W4313200877 title "ZIF-L-derived C-doped ZnO via a two-step calcination for enhanced photocatalytic hydrogen evolution" @default.
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- W4313200877 doi "https://doi.org/10.1016/j.molstruc.2022.134787" @default.
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