Matches in SemOpenAlex for { <https://semopenalex.org/work/W4313203926> ?p ?o ?g. }
- W4313203926 endingPage "1066" @default.
- W4313203926 startingPage "1056" @default.
- W4313203926 abstract "Strategies for the sustainable synthesis of redox-active organic polymers could lead to next-generation organic electrode materials for electrochemical energy storage, electrocatalysis, and electro-swing chemical separations. Among redox-active moieties, benzils or aromatic 1,2-diones are particularly attractive due to their high theoretical gravimetric capacities and fast charge/discharge rates. Herein, we demonstrate that the cyanide-catalyzed polymerization of simple dialdehyde monomers unexpectedly leads to insoluble redox-active benzil-linked polymers instead of the expected benzoin polymers, as supported by solid-state nuclear magnetic resonance spectroscopy and electrochemical characterization. Mechanistic studies suggest that cyanide-mediated benzoin oxidation occurs by hydride transfer to the solvent and that the insolubility of the benzil-linked polymers protects them from subsequent cyanolysis. The thiophene-based polymer poly(BTDA) is an intriguing organic electrode material that demonstrates two reversible one-electron reductions with monovalent cations such as Li+ and Na+ but one two-electron reduction with divalent Mg2+. As such, the tandem benzoin-oxidation polymerization reported herein represents a sustainable method for the synthesis of highly tunable and redox-active organic materials." @default.
- W4313203926 created "2023-01-06" @default.
- W4313203926 creator A5002804366 @default.
- W4313203926 creator A5013982088 @default.
- W4313203926 creator A5026531765 @default.
- W4313203926 creator A5032986580 @default.
- W4313203926 creator A5042053197 @default.
- W4313203926 date "2022-12-28" @default.
- W4313203926 modified "2023-10-14" @default.
- W4313203926 title "Unexpected Direct Synthesis of Tunable Redox-Active Benzil-Linked Polymers via the Benzoin Reaction" @default.
- W4313203926 cites W1599951015 @default.
- W4313203926 cites W1973383756 @default.
- W4313203926 cites W1982750759 @default.
- W4313203926 cites W1995113720 @default.
- W4313203926 cites W2000581562 @default.
- W4313203926 cites W2005877813 @default.
- W4313203926 cites W2016256656 @default.
- W4313203926 cites W2019341438 @default.
- W4313203926 cites W2025340602 @default.
- W4313203926 cites W2031771135 @default.
- W4313203926 cites W2037303959 @default.
- W4313203926 cites W2070677362 @default.
- W4313203926 cites W2080705494 @default.
- W4313203926 cites W2081030985 @default.
- W4313203926 cites W2083371817 @default.
- W4313203926 cites W2091875228 @default.
- W4313203926 cites W2102196887 @default.
- W4313203926 cites W2125576202 @default.
- W4313203926 cites W2125827894 @default.
- W4313203926 cites W2165738701 @default.
- W4313203926 cites W2312872516 @default.
- W4313203926 cites W2326201485 @default.
- W4313203926 cites W2328285822 @default.
- W4313203926 cites W2337365156 @default.
- W4313203926 cites W2408382927 @default.
- W4313203926 cites W2411524973 @default.
- W4313203926 cites W2414107837 @default.
- W4313203926 cites W2477010509 @default.
- W4313203926 cites W2591744926 @default.
- W4313203926 cites W2611147606 @default.
- W4313203926 cites W2612045712 @default.
- W4313203926 cites W2753846411 @default.
- W4313203926 cites W2794630090 @default.
- W4313203926 cites W2795074072 @default.
- W4313203926 cites W2803266028 @default.
- W4313203926 cites W2886710866 @default.
- W4313203926 cites W2890907521 @default.
- W4313203926 cites W2895970620 @default.
- W4313203926 cites W2896631582 @default.
- W4313203926 cites W2900437390 @default.
- W4313203926 cites W2932478038 @default.
- W4313203926 cites W2938000819 @default.
- W4313203926 cites W2947264857 @default.
- W4313203926 cites W2949247207 @default.
- W4313203926 cites W2952900675 @default.
- W4313203926 cites W2956716589 @default.
- W4313203926 cites W2972332244 @default.
- W4313203926 cites W2978618128 @default.
- W4313203926 cites W3002337695 @default.
- W4313203926 cites W3007852434 @default.
- W4313203926 cites W3039522137 @default.
- W4313203926 cites W3049714641 @default.
- W4313203926 cites W3089105587 @default.
- W4313203926 cites W3089505223 @default.
- W4313203926 cites W3090089932 @default.
- W4313203926 cites W3097741159 @default.
- W4313203926 cites W3120104539 @default.
- W4313203926 cites W3120285716 @default.
- W4313203926 cites W3124385340 @default.
- W4313203926 cites W3124959881 @default.
- W4313203926 cites W3128230384 @default.
- W4313203926 cites W3154409837 @default.
- W4313203926 cites W3159610571 @default.
- W4313203926 cites W3161271968 @default.
- W4313203926 cites W3164483471 @default.
- W4313203926 cites W4210922543 @default.
- W4313203926 cites W4280652030 @default.
- W4313203926 cites W4285221525 @default.
- W4313203926 doi "https://doi.org/10.1021/acsapm.2c02047" @default.
- W4313203926 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37123564" @default.
- W4313203926 hasPublicationYear "2022" @default.
- W4313203926 type Work @default.
- W4313203926 citedByCount "0" @default.
- W4313203926 crossrefType "journal-article" @default.
- W4313203926 hasAuthorship W4313203926A5002804366 @default.
- W4313203926 hasAuthorship W4313203926A5013982088 @default.
- W4313203926 hasAuthorship W4313203926A5026531765 @default.
- W4313203926 hasAuthorship W4313203926A5032986580 @default.
- W4313203926 hasAuthorship W4313203926A5042053197 @default.
- W4313203926 hasConcept C161790260 @default.
- W4313203926 hasConcept C178790620 @default.
- W4313203926 hasConcept C185592680 @default.
- W4313203926 hasConcept C188027245 @default.
- W4313203926 hasConcept C21951064 @default.
- W4313203926 hasConcept C2776455741 @default.
- W4313203926 hasConcept C2777230457 @default.
- W4313203926 hasConcept C44228677 @default.
- W4313203926 hasConcept C521977710 @default.