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- W4313214972 abstract "The development of functional material is significant to remove heavy metal ions from water environment. Herein, macroporous adsorption resin (MAR) of poly(glycidyl methacrylate-co-ethylene dimethacrylate) (poly(GMA-co-EDMA)) was selected as a substrate. Then, a functional monomer, 3-(triallylsilyl)propyl acrylate (TAPA), possessing three alkenyl groups, was grafted onto the surface of MAR via surface-initiated atom transfer radical polymerization (SI-ATRP). Subsequently, a kind of carbon dot (CD) with blue fluorescence fabricated with malonic acid and glutathione as precursors was anchored onto the surface of MAR to produce a bi-functional resin, assigned as [email protected](TAPA)-CD. Owning to fluorescence property of [email protected](TAPA)-CD and presenting different fluorescence quenching for metal ions, especially for Fe3+ ions, the degree of quenching reached 46.2%. A linear range for 10–80 nmol L−1 (correlation coefficient of 0.9909) was acquired, meanwhile, the limit of detection about 9.74 nmol L−1 was measured, which could be applied in the trace detection. In addition, the functionalized [email protected](TAPA)-CD was also utilized in adsorption of Fe3+ ion, and exhibited high adsorption capacity of 32.9 mg g−1. The equilibrium time for adsorption of Fe3+ occurred at 45 min. Thus, the bifunctional material can simultaneously achieve detection and adsorption of Fe3+ ion in aqueous solution, demonstrating great potential for commercialization." @default.
- W4313214972 created "2023-01-06" @default.
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- W4313214972 date "2023-03-01" @default.
- W4313214972 modified "2023-10-17" @default.
- W4313214972 title "Fabrication of bifunctional macroporous adsorption resin via grafting carbon dot and application in the detection and adsorption of iron (III) ion" @default.
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- W4313214972 doi "https://doi.org/10.1016/j.mtcomm.2022.105220" @default.
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