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- W4313222796 abstract "Polyoxometalate (POM) clusters with atomic precision structures are promising candidates construct functional nanomaterials via self-assembly. Non-covalent interactions at molecular levels can govern the self-assembly of POM clusters, for which the precise control of POM-based assemblies can be realized at single-cluster levels. This mini-review focuses on the synthesis and properties of POM-based nanostructures, including amphiphilic POM assemblies and co-assemblies of POM clusters and other subnanometer building blocks. Several synthetic strategies have been developed for rational control of POM-based assemblies in terms of morphologies, compositions and properties. 1D subnanometer POM assemblies demonstrate remarkable enhanced mechanical properties due to the topological interactions between nanowires and surroundings. The in-depth understanding of POM-based assemblies may help in the design of functional nanomaterials in fundamental perspectives and applications." @default.
- W4313222796 created "2023-01-06" @default.
- W4313222796 creator A5010804247 @default.
- W4313222796 creator A5017080892 @default.
- W4313222796 date "2023-01-18" @default.
- W4313222796 modified "2023-10-17" @default.
- W4313222796 title "Precise Assembly of Polyoxometalates at Single‐cluster Levels" @default.
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- W4313222796 doi "https://doi.org/10.1002/anie.202217764" @default.