Matches in SemOpenAlex for { <https://semopenalex.org/work/W4313231609> ?p ?o ?g. }
- W4313231609 endingPage "713" @default.
- W4313231609 startingPage "704" @default.
- W4313231609 abstract "The development of catalytic systems with different chemo- and biocatalytic functionalities for sustainable one-pot multistep transformations represents a big challenge in modern chemistry. Here, we have designed and synthesized enzyme-metal hybrids’ materials of palladium and copper as multiactive heterogeneous catalysts. The in situ formation of metallic nanoparticles of different size and species on multilayer graphene-anchored Candida antarctica lipase (G@CALB) at room temperature and aqueous media allowed creation of different kinds of enzyme-metal nanoarchitectures, where the metal nanoparticles were synthesized exclusively when induced by an enzyme, dispersed homogeneously on the enzyme structure as the scaffold. The creation of copper or palladium nanoparticles on the graphene-enzyme preparation allowed obtaining a new type of enzyme-metal bifunctional catalyst conserving the enzymatic activity intact and enhancing the metallic properties. Furthermore, the creation of a CuPd alloy on immobilized enzyme preparation (G@CALB-PdNPs-CuNPs) allowed obtaining a new enzyme-bimetallic trifunctional catalyst, with extremely enhanced metallic activity by the synergistic effect. These hybrids were successfully applied in different cascade processes, where the hybrid G@CALB-PdNPs-CuNPs, based on its property, showed superior efficiency to bifunctional hybrids in the regioselective and asymmetric one-pot tandem processes tested." @default.
- W4313231609 created "2023-01-06" @default.
- W4313231609 creator A5028391028 @default.
- W4313231609 creator A5071258591 @default.
- W4313231609 creator A5083225216 @default.
- W4313231609 date "2022-12-28" @default.
- W4313231609 modified "2023-10-18" @default.
- W4313231609 title "Metal Nanoparticles Incorporated within Graphene-Enzyme Preparations for Synergistic Multiactive Catalysts" @default.
- W4313231609 cites W1771630980 @default.
- W4313231609 cites W2008444433 @default.
- W4313231609 cites W2012361744 @default.
- W4313231609 cites W2027563442 @default.
- W4313231609 cites W2033495093 @default.
- W4313231609 cites W2039716232 @default.
- W4313231609 cites W2063295313 @default.
- W4313231609 cites W2082003346 @default.
- W4313231609 cites W2104508995 @default.
- W4313231609 cites W2156313886 @default.
- W4313231609 cites W2591861249 @default.
- W4313231609 cites W2751743037 @default.
- W4313231609 cites W2785293120 @default.
- W4313231609 cites W2803422123 @default.
- W4313231609 cites W2903540663 @default.
- W4313231609 cites W2912459103 @default.
- W4313231609 cites W2943223638 @default.
- W4313231609 cites W2952592131 @default.
- W4313231609 cites W2963465829 @default.
- W4313231609 cites W2970620508 @default.
- W4313231609 cites W2974498073 @default.
- W4313231609 cites W2991154351 @default.
- W4313231609 cites W2995356079 @default.
- W4313231609 cites W2998598385 @default.
- W4313231609 cites W3021121331 @default.
- W4313231609 cites W3030594500 @default.
- W4313231609 cites W3033383729 @default.
- W4313231609 cites W3097208626 @default.
- W4313231609 cites W3101488014 @default.
- W4313231609 cites W3115263024 @default.
- W4313231609 cites W3118627377 @default.
- W4313231609 cites W3135689823 @default.
- W4313231609 cites W3155070156 @default.
- W4313231609 cites W3156345085 @default.
- W4313231609 cites W3181671806 @default.
- W4313231609 cites W3187726155 @default.
- W4313231609 cites W4205145893 @default.
- W4313231609 cites W4220966521 @default.
- W4313231609 doi "https://doi.org/10.1021/acsanm.2c04963" @default.
- W4313231609 hasPublicationYear "2022" @default.
- W4313231609 type Work @default.
- W4313231609 citedByCount "2" @default.
- W4313231609 countsByYear W43132316092023 @default.
- W4313231609 crossrefType "journal-article" @default.
- W4313231609 hasAuthorship W4313231609A5028391028 @default.
- W4313231609 hasAuthorship W4313231609A5071258591 @default.
- W4313231609 hasAuthorship W4313231609A5083225216 @default.
- W4313231609 hasConcept C127413603 @default.
- W4313231609 hasConcept C155672457 @default.
- W4313231609 hasConcept C161790260 @default.
- W4313231609 hasConcept C171250308 @default.
- W4313231609 hasConcept C178790620 @default.
- W4313231609 hasConcept C181199279 @default.
- W4313231609 hasConcept C185592680 @default.
- W4313231609 hasConcept C192562407 @default.
- W4313231609 hasConcept C21951064 @default.
- W4313231609 hasConcept C2779542420 @default.
- W4313231609 hasConcept C2779697368 @default.
- W4313231609 hasConcept C2780443040 @default.
- W4313231609 hasConcept C30080830 @default.
- W4313231609 hasConcept C33633552 @default.
- W4313231609 hasConcept C42360764 @default.
- W4313231609 hasConcept C43411465 @default.
- W4313231609 hasConcept C502130503 @default.
- W4313231609 hasConcept C544153396 @default.
- W4313231609 hasConcept C544778455 @default.
- W4313231609 hasConceptScore W4313231609C127413603 @default.
- W4313231609 hasConceptScore W4313231609C155672457 @default.
- W4313231609 hasConceptScore W4313231609C161790260 @default.
- W4313231609 hasConceptScore W4313231609C171250308 @default.
- W4313231609 hasConceptScore W4313231609C178790620 @default.
- W4313231609 hasConceptScore W4313231609C181199279 @default.
- W4313231609 hasConceptScore W4313231609C185592680 @default.
- W4313231609 hasConceptScore W4313231609C192562407 @default.
- W4313231609 hasConceptScore W4313231609C21951064 @default.
- W4313231609 hasConceptScore W4313231609C2779542420 @default.
- W4313231609 hasConceptScore W4313231609C2779697368 @default.
- W4313231609 hasConceptScore W4313231609C2780443040 @default.
- W4313231609 hasConceptScore W4313231609C30080830 @default.
- W4313231609 hasConceptScore W4313231609C33633552 @default.
- W4313231609 hasConceptScore W4313231609C42360764 @default.
- W4313231609 hasConceptScore W4313231609C43411465 @default.
- W4313231609 hasConceptScore W4313231609C502130503 @default.
- W4313231609 hasConceptScore W4313231609C544153396 @default.
- W4313231609 hasConceptScore W4313231609C544778455 @default.
- W4313231609 hasFunder F4320320300 @default.
- W4313231609 hasFunder F4320322930 @default.
- W4313231609 hasFunder F4320326208 @default.
- W4313231609 hasFunder F4320334857 @default.
- W4313231609 hasIssue "1" @default.