Matches in SemOpenAlex for { <https://semopenalex.org/work/W4313232235> ?p ?o ?g. }
- W4313232235 endingPage "144" @default.
- W4313232235 startingPage "144" @default.
- W4313232235 abstract "New nanocomposite materials with UV-NIR blocking properties and hues ranging from green to brown were prepared by integrating inorganic tantalum octahedral cluster building blocks prepared via solid-state chemistry in a PMMA matrix. After the synthesis by the solid-state chemical reaction of the K4[{Ta6Bri12}Bra6] ternary halide, built-up from [{Ta6Bri12}Bra6]4- anionic building blocks, and potassium cations, the potassium cations were replaced by functional organic cations (Kat+) bearing a methacrylate function. The resulting intermediate, (Kat)2[{Ta6Bri12}Bra6], was then incorporated homogeneously by copolymerization with MMA into transparent PMMA matrices to form a brown transparent hybrid composite Ta@PMMAbrown. The color of the composites was tuned by controlling the charge and consequently the oxidation state of the cluster building block. Ta@PMMAgreen was obtained through the two-electron reduction of the [{Ta6Bri12}Bra6]2- building blocks from Ta@PMMAbrown in solution. Indeed, the control of the oxidation state of the Ta6 cluster inorganic building blocks occurred inside the copolymer, which not only allowed the tuning of the optical properties of the composite in the visible region but also allowed the tuning of its UV and NIR blocking properties." @default.
- W4313232235 created "2023-01-06" @default.
- W4313232235 creator A5032465783 @default.
- W4313232235 creator A5043946830 @default.
- W4313232235 creator A5048042027 @default.
- W4313232235 creator A5064000112 @default.
- W4313232235 creator A5065643307 @default.
- W4313232235 creator A5077976821 @default.
- W4313232235 creator A5079724999 @default.
- W4313232235 date "2022-12-28" @default.
- W4313232235 modified "2023-10-14" @default.
- W4313232235 title "From Solid-State Cluster Compounds to Functional PMMA-Based Composites with UV and NIR Blocking Properties, and Tuned Hues" @default.
- W4313232235 cites W1795281546 @default.
- W4313232235 cites W1875842200 @default.
- W4313232235 cites W1971032933 @default.
- W4313232235 cites W1972384112 @default.
- W4313232235 cites W1975460230 @default.
- W4313232235 cites W1975596362 @default.
- W4313232235 cites W1986548614 @default.
- W4313232235 cites W2000726383 @default.
- W4313232235 cites W2004428922 @default.
- W4313232235 cites W2005379132 @default.
- W4313232235 cites W2005744558 @default.
- W4313232235 cites W2008706380 @default.
- W4313232235 cites W2008914183 @default.
- W4313232235 cites W2016175015 @default.
- W4313232235 cites W2029166048 @default.
- W4313232235 cites W2030559530 @default.
- W4313232235 cites W2030759159 @default.
- W4313232235 cites W2034555791 @default.
- W4313232235 cites W2035770745 @default.
- W4313232235 cites W2036169932 @default.
- W4313232235 cites W2036601049 @default.
- W4313232235 cites W2042568342 @default.
- W4313232235 cites W2043742608 @default.
- W4313232235 cites W2057184512 @default.
- W4313232235 cites W2057863409 @default.
- W4313232235 cites W2064491704 @default.
- W4313232235 cites W2066276319 @default.
- W4313232235 cites W2066713480 @default.
- W4313232235 cites W2069067941 @default.
- W4313232235 cites W2069858887 @default.
- W4313232235 cites W2072194008 @default.
- W4313232235 cites W2072913529 @default.
- W4313232235 cites W2075680228 @default.
- W4313232235 cites W2089863636 @default.
- W4313232235 cites W2100020382 @default.
- W4313232235 cites W2118074071 @default.
- W4313232235 cites W2129995799 @default.
- W4313232235 cites W2167730668 @default.
- W4313232235 cites W2168506240 @default.
- W4313232235 cites W2169753878 @default.
- W4313232235 cites W2287937912 @default.
- W4313232235 cites W2322565164 @default.
- W4313232235 cites W2325240333 @default.
- W4313232235 cites W2333850181 @default.
- W4313232235 cites W2429209199 @default.
- W4313232235 cites W2468821776 @default.
- W4313232235 cites W2515690357 @default.
- W4313232235 cites W2733751816 @default.
- W4313232235 cites W2736041594 @default.
- W4313232235 cites W2760486784 @default.
- W4313232235 cites W2763178940 @default.
- W4313232235 cites W2791687623 @default.
- W4313232235 cites W2876933902 @default.
- W4313232235 cites W2905239322 @default.
- W4313232235 cites W2949239119 @default.
- W4313232235 cites W2952921109 @default.
- W4313232235 cites W3036755652 @default.
- W4313232235 cites W3138244097 @default.
- W4313232235 cites W3161214769 @default.
- W4313232235 cites W3162727743 @default.
- W4313232235 cites W3166829352 @default.
- W4313232235 cites W3166908092 @default.
- W4313232235 cites W4200426945 @default.
- W4313232235 cites W4226367331 @default.
- W4313232235 cites W4283020628 @default.
- W4313232235 cites W4289869606 @default.
- W4313232235 cites W4294000340 @default.
- W4313232235 cites W4306764885 @default.
- W4313232235 doi "https://doi.org/10.3390/nano13010144" @default.
- W4313232235 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36616054" @default.
- W4313232235 hasPublicationYear "2022" @default.
- W4313232235 type Work @default.
- W4313232235 citedByCount "0" @default.
- W4313232235 crossrefType "journal-article" @default.
- W4313232235 hasAuthorship W4313232235A5032465783 @default.
- W4313232235 hasAuthorship W4313232235A5043946830 @default.
- W4313232235 hasAuthorship W4313232235A5048042027 @default.
- W4313232235 hasAuthorship W4313232235A5064000112 @default.
- W4313232235 hasAuthorship W4313232235A5065643307 @default.
- W4313232235 hasAuthorship W4313232235A5077976821 @default.
- W4313232235 hasAuthorship W4313232235A5079724999 @default.
- W4313232235 hasBestOaLocation W43132322351 @default.
- W4313232235 hasConcept C104779481 @default.
- W4313232235 hasConcept C127413603 @default.
- W4313232235 hasConcept C15920480 @default.
- W4313232235 hasConcept C159985019 @default.