Matches in SemOpenAlex for { <https://semopenalex.org/work/W4313236719> ?p ?o ?g. }
- W4313236719 endingPage "1234" @default.
- W4313236719 startingPage "1227" @default.
- W4313236719 abstract "The functionalization of sp3 carbons is deemed challenging in synthetic organic chemistry yet has tremendous potential in producing potent organic compounds. A facile synthesis of 2,4,5-trisubstituted oxazoles through an oxidative, copper-catalyzed, and solvent-free annulation is described. Various arylated oxazoles were efficaciously synthesized at a mild temperature from readily available substrates under a molecular oxygen atmosphere. Preliminary mechanistic studies suggested that the reaction proceeds via an anionic-type mechanism and indicated the formation of a keto–imine intermediate. The reaction is notable for the abstraction of six hydrogen atoms, the functionalization of one sp2 carbon and two sp3 carbons, and the formation of C–O and C–N bonds." @default.
- W4313236719 created "2023-01-06" @default.
- W4313236719 creator A5035652404 @default.
- W4313236719 creator A5061197490 @default.
- W4313236719 date "2022-12-27" @default.
- W4313236719 modified "2023-10-18" @default.
- W4313236719 title "Synthesis of 2,4,5-Trisubstituted Oxazoles from Copper-Mediated Benzylic sp<sup>3</sup> C–H Aerobic Oxidative Annulation of Ketones and Amines via a Cascade Reaction" @default.
- W4313236719 cites W1200875517 @default.
- W4313236719 cites W1975607600 @default.
- W4313236719 cites W1977036873 @default.
- W4313236719 cites W1989833012 @default.
- W4313236719 cites W2007325349 @default.
- W4313236719 cites W2012251006 @default.
- W4313236719 cites W2019169667 @default.
- W4313236719 cites W2045652811 @default.
- W4313236719 cites W2056811030 @default.
- W4313236719 cites W2059406108 @default.
- W4313236719 cites W2074564459 @default.
- W4313236719 cites W2081048082 @default.
- W4313236719 cites W2083109823 @default.
- W4313236719 cites W2083990575 @default.
- W4313236719 cites W2084870462 @default.
- W4313236719 cites W2134066714 @default.
- W4313236719 cites W2146465377 @default.
- W4313236719 cites W2150338396 @default.
- W4313236719 cites W2156281639 @default.
- W4313236719 cites W2158227388 @default.
- W4313236719 cites W2163847388 @default.
- W4313236719 cites W2321846427 @default.
- W4313236719 cites W2468356389 @default.
- W4313236719 cites W2551732461 @default.
- W4313236719 cites W2560121484 @default.
- W4313236719 cites W2594736913 @default.
- W4313236719 cites W2596225980 @default.
- W4313236719 cites W2741314367 @default.
- W4313236719 cites W2747389794 @default.
- W4313236719 cites W2770803971 @default.
- W4313236719 cites W2889794826 @default.
- W4313236719 cites W2912288706 @default.
- W4313236719 cites W2913267641 @default.
- W4313236719 cites W2922106996 @default.
- W4313236719 cites W2924587480 @default.
- W4313236719 cites W2949568939 @default.
- W4313236719 cites W2950553420 @default.
- W4313236719 cites W2951532151 @default.
- W4313236719 cites W2951663130 @default.
- W4313236719 cites W2967537587 @default.
- W4313236719 cites W2973577277 @default.
- W4313236719 cites W2983844837 @default.
- W4313236719 cites W3015980346 @default.
- W4313236719 cites W3082499071 @default.
- W4313236719 cites W3094427468 @default.
- W4313236719 cites W3113586818 @default.
- W4313236719 cites W3131531402 @default.
- W4313236719 cites W3138886327 @default.
- W4313236719 cites W3139066592 @default.
- W4313236719 cites W3157755951 @default.
- W4313236719 cites W3161449787 @default.
- W4313236719 cites W3188910544 @default.
- W4313236719 cites W3206279809 @default.
- W4313236719 cites W4281955472 @default.
- W4313236719 cites W4283715204 @default.
- W4313236719 cites W4289786560 @default.
- W4313236719 doi "https://doi.org/10.1021/acs.joc.2c02148" @default.
- W4313236719 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36575054" @default.
- W4313236719 hasPublicationYear "2022" @default.
- W4313236719 type Work @default.
- W4313236719 citedByCount "2" @default.
- W4313236719 countsByYear W43132367192023 @default.
- W4313236719 crossrefType "journal-article" @default.
- W4313236719 hasAuthorship W4313236719A5035652404 @default.
- W4313236719 hasAuthorship W4313236719A5061197490 @default.
- W4313236719 hasConcept C115537861 @default.
- W4313236719 hasConcept C147789679 @default.
- W4313236719 hasConcept C155647269 @default.
- W4313236719 hasConcept C161790260 @default.
- W4313236719 hasConcept C178790620 @default.
- W4313236719 hasConcept C185592680 @default.
- W4313236719 hasConcept C21951064 @default.
- W4313236719 hasConcept C2776573223 @default.
- W4313236719 hasConcept C512968161 @default.
- W4313236719 hasConcept C544778455 @default.
- W4313236719 hasConcept C7512685 @default.
- W4313236719 hasConcept C81022585 @default.
- W4313236719 hasConceptScore W4313236719C115537861 @default.
- W4313236719 hasConceptScore W4313236719C147789679 @default.
- W4313236719 hasConceptScore W4313236719C155647269 @default.
- W4313236719 hasConceptScore W4313236719C161790260 @default.
- W4313236719 hasConceptScore W4313236719C178790620 @default.
- W4313236719 hasConceptScore W4313236719C185592680 @default.
- W4313236719 hasConceptScore W4313236719C21951064 @default.
- W4313236719 hasConceptScore W4313236719C2776573223 @default.
- W4313236719 hasConceptScore W4313236719C512968161 @default.
- W4313236719 hasConceptScore W4313236719C544778455 @default.
- W4313236719 hasConceptScore W4313236719C7512685 @default.
- W4313236719 hasConceptScore W4313236719C81022585 @default.
- W4313236719 hasFunder F4320335132 @default.
- W4313236719 hasIssue "2" @default.