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- W4313236847 abstract "Bisborylalkanes play important roles in organic synthesis as versatile bifunctional reagents. The two boron moieties in these compounds can be selectively converted into other functional groups through cross-coupling, oxidation or radical reactions. Thus, the development of efficient methods for synthesizing bisborylalkanes is highly demanded. Herein we report a new strategy to access bisborylalkanes through the reaction of N-trisylhydrazones with diboronate, in which the bis(boryl) methane is transformed into 1,2-bis(boronates) via formal carbene insertion. Since the N-trisylhydrazones can be readily derived from the corresponding aldehydes, this strategy represents a practical synthesis of 1,2-diboronates with broad substrate scope. Mechanistic studies reveal an unusual neighboring group effect of 1,1-bis(boronates), which accounts for the observed regioselectivity when unsymmetric 1,1-diboronates are applied." @default.
- W4313236847 created "2023-01-06" @default.
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- W4313236847 date "2023-01-24" @default.
- W4313236847 modified "2023-10-14" @default.
- W4313236847 title "Selective Formal Carbene Insertion into Carbon‐Boron Bonds of Diboronates by <i>N</i>‐Trisylhydrazones" @default.
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- W4313236847 doi "https://doi.org/10.1002/anie.202216356" @default.
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