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- W4313237053 abstract "Thorium redox chemistry is extremely scarce due to the high stability of ThIV . Here we report two unique examples of thorium arenide complexes prepared by reduction of a ThIV -siloxide complex in presence of naphthalene, the mononuclear arenide complex [K(OSi(Ot Bu)3 )3 Th(η6 -C10 H8 )] (1) and the inverse-sandwich complex [K(OSi(Ot Bu)3 )3 Th]2 (μ-η6 ,η6 -C10 H8 )] (2). The electrons stored in these complexes allow the reduction of a broad range of substrates (N2 O, AdN3 , CO2 , HBBN). Higher reactivity was found for the complex 1 which reacts with the diazoolefin IDipp=CN2 to yield the unexpected ThIV amidoalkynyl complex 5 via a terminal N-heterocyclic vinylidene intermediate. This work showed that arenides can act as convenient redox-active ligands for implementing thorium-ligand cooperative multielectron transfer and that the reactivity can be tuned by the arenide binding mode." @default.
- W4313237053 created "2023-01-06" @default.
- W4313237053 creator A5001181915 @default.
- W4313237053 creator A5006785866 @default.
- W4313237053 creator A5025455387 @default.
- W4313237053 creator A5033332794 @default.
- W4313237053 creator A5041809573 @default.
- W4313237053 creator A5065155647 @default.
- W4313237053 creator A5076299300 @default.
- W4313237053 creator A5086637541 @default.
- W4313237053 date "2023-01-18" @default.
- W4313237053 modified "2023-10-14" @default.
- W4313237053 title "Bonding and Reactivity in Terminal versus Bridging Arenide Complexes of Thorium Acting as Th<sup>II</sup> Synthons" @default.
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- W4313237053 doi "https://doi.org/10.1002/anie.202215846" @default.