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- W4313237418 abstract "Spiro[indole-3,3′-pyrrolidine]-2′-ones were synthesized via one-pot chloroformylation-dearomatizing spirocyclization of tryptamine derivatives. Moreover, the “thio” equivalent spiro[indole-3,3′-pyrrolidine]-2′-thiones, for which the synthesis and properties were previously unreported, were synthesized. The procedures are easily implemented, have a broad scope, and are transition-metal-free and cheap. To demonstrate the utility of the synthetic methodology, the spiro[indole-3,3′-pyrrolidine]-2′-ones were converted into heterocyclic scaffolds, such as an optically active spiroindoline and spirooxindole." @default.
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- W4313237418 date "2022-12-28" @default.
- W4313237418 modified "2023-10-16" @default.
- W4313237418 title "Synthesis of Spiro[indole-3,3′-pyrrolidine]-2′-(thi)ones" @default.
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- W4313237418 doi "https://doi.org/10.1021/acs.joc.2c02561" @default.
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