Matches in SemOpenAlex for { <https://semopenalex.org/work/W4313251330> ?p ?o ?g. }
- W4313251330 abstract "Abstract The open circuit potential (OCP) established by the quasi-equilibrated electrode reaction of H 2 and H 3 O + (hydr.) , complicates catalytic reactions significantly. The hydrogenolysis rate of benzylic alcohol on Pd/C increases 2-3 orders of magnitude with the pH decreasing from 7 to 0.6. The reaction follows a pathway of protonated benzyl alcohol dehydration to a benzylic carbenium ion, followed by a hydride addition to form toluene. The dehydration of protonated benzyl alcohol is kinetic relevent, thus, being enhanced at lower pH. The OCP stabilizes all cationic species in the elementary steps. Particularly, the initial state (benzyl alcohol oxonium ion) is less stabilized than the dehydration transition state and the product (benzylic carbenium), thus, lowering the free energy barrier of the rate-determining step. In accordance, the rate increased with increasingly negative OCP. Beside OCP, an external negative electric potential in an electrocatlaytic system was also demonstrated to enhance the rate in the same way." @default.
- W4313251330 created "2023-01-06" @default.
- W4313251330 creator A5001937247 @default.
- W4313251330 creator A5007221358 @default.
- W4313251330 creator A5014382925 @default.
- W4313251330 creator A5020140367 @default.
- W4313251330 creator A5051053074 @default.
- W4313251330 creator A5073658390 @default.
- W4313251330 creator A5076699095 @default.
- W4313251330 date "2022-12-27" @default.
- W4313251330 modified "2023-09-30" @default.
- W4313251330 title "Importance of interface open circuit potential on aqueous hydrogenolytic reduction of benzyl alcohol over Pd/C" @default.
- W4313251330 cites W1971385028 @default.
- W4313251330 cites W1980037168 @default.
- W4313251330 cites W1988861048 @default.
- W4313251330 cites W1994432739 @default.
- W4313251330 cites W1998321859 @default.
- W4313251330 cites W2002529545 @default.
- W4313251330 cites W2004127836 @default.
- W4313251330 cites W2017204504 @default.
- W4313251330 cites W2025496176 @default.
- W4313251330 cites W2035984142 @default.
- W4313251330 cites W2036268878 @default.
- W4313251330 cites W2037820199 @default.
- W4313251330 cites W2060262517 @default.
- W4313251330 cites W2061712538 @default.
- W4313251330 cites W2083666831 @default.
- W4313251330 cites W2112281851 @default.
- W4313251330 cites W2322722095 @default.
- W4313251330 cites W2410058203 @default.
- W4313251330 cites W2788759813 @default.
- W4313251330 cites W2793197557 @default.
- W4313251330 cites W2793536176 @default.
- W4313251330 cites W2804582780 @default.
- W4313251330 cites W2895121450 @default.
- W4313251330 cites W2901440519 @default.
- W4313251330 cites W2904956365 @default.
- W4313251330 cites W2929517860 @default.
- W4313251330 cites W2969500574 @default.
- W4313251330 cites W2982034149 @default.
- W4313251330 cites W3048159140 @default.
- W4313251330 cites W3087269616 @default.
- W4313251330 cites W3090462502 @default.
- W4313251330 cites W3091837684 @default.
- W4313251330 cites W3092187489 @default.
- W4313251330 cites W3214004234 @default.
- W4313251330 cites W4243690873 @default.
- W4313251330 doi "https://doi.org/10.1038/s41467-022-35554-1" @default.
- W4313251330 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36575187" @default.
- W4313251330 hasPublicationYear "2022" @default.
- W4313251330 type Work @default.
- W4313251330 citedByCount "6" @default.
- W4313251330 countsByYear W43132513302023 @default.
- W4313251330 crossrefType "journal-article" @default.
- W4313251330 hasAuthorship W4313251330A5001937247 @default.
- W4313251330 hasAuthorship W4313251330A5007221358 @default.
- W4313251330 hasAuthorship W4313251330A5014382925 @default.
- W4313251330 hasAuthorship W4313251330A5020140367 @default.
- W4313251330 hasAuthorship W4313251330A5051053074 @default.
- W4313251330 hasAuthorship W4313251330A5073658390 @default.
- W4313251330 hasAuthorship W4313251330A5076699095 @default.
- W4313251330 hasBestOaLocation W43132513301 @default.
- W4313251330 hasConcept C145148216 @default.
- W4313251330 hasConcept C155647269 @default.
- W4313251330 hasConcept C161790260 @default.
- W4313251330 hasConcept C178386823 @default.
- W4313251330 hasConcept C178790620 @default.
- W4313251330 hasConcept C181886296 @default.
- W4313251330 hasConcept C183882617 @default.
- W4313251330 hasConcept C184651966 @default.
- W4313251330 hasConcept C185592680 @default.
- W4313251330 hasConcept C2776460118 @default.
- W4313251330 hasConcept C2777463211 @default.
- W4313251330 hasConcept C2778142098 @default.
- W4313251330 hasConcept C2781066024 @default.
- W4313251330 hasConcept C30095370 @default.
- W4313251330 hasConcept C75473681 @default.
- W4313251330 hasConceptScore W4313251330C145148216 @default.
- W4313251330 hasConceptScore W4313251330C155647269 @default.
- W4313251330 hasConceptScore W4313251330C161790260 @default.
- W4313251330 hasConceptScore W4313251330C178386823 @default.
- W4313251330 hasConceptScore W4313251330C178790620 @default.
- W4313251330 hasConceptScore W4313251330C181886296 @default.
- W4313251330 hasConceptScore W4313251330C183882617 @default.
- W4313251330 hasConceptScore W4313251330C184651966 @default.
- W4313251330 hasConceptScore W4313251330C185592680 @default.
- W4313251330 hasConceptScore W4313251330C2776460118 @default.
- W4313251330 hasConceptScore W4313251330C2777463211 @default.
- W4313251330 hasConceptScore W4313251330C2778142098 @default.
- W4313251330 hasConceptScore W4313251330C2781066024 @default.
- W4313251330 hasConceptScore W4313251330C30095370 @default.
- W4313251330 hasConceptScore W4313251330C75473681 @default.
- W4313251330 hasFunder F4320337480 @default.
- W4313251330 hasIssue "1" @default.
- W4313251330 hasLocation W43132513301 @default.
- W4313251330 hasLocation W43132513302 @default.
- W4313251330 hasLocation W43132513303 @default.
- W4313251330 hasLocation W43132513304 @default.
- W4313251330 hasLocation W43132513305 @default.
- W4313251330 hasOpenAccess W4313251330 @default.