Matches in SemOpenAlex for { <https://semopenalex.org/work/W4313252118> ?p ?o ?g. }
- W4313252118 endingPage "1710" @default.
- W4313252118 startingPage "1704" @default.
- W4313252118 abstract "Despite recent progress regarding the metal-catalyzed C–N cross-coupling of (hetero)aryl (pseudo)halides with NH substrates, such transformations involving sulfinamide nucleophiles are underdeveloped. Herein we report on Ni-catalyzed C–N cross-couplings of this type, employing primarily tert-butanesulfinamide (i.e., Ellman’s sulfinamide) as a test nucleophile. Inexpensive and abundant (hetero)aryl chlorides proved to be suitable reaction partners in such reactions when using (L)Ni(o-tol)Cl (L = CyPAd-DalPhos or PhPAd-DalPhos) precatalysts. We also present results of an experimental and computational study focusing on C–N reductive elimination involving newly prepared and isolated sulfinamido (L)Ni(o-tol)(NHS(O)tBu) complexes, in which deprotonation leading to the formation of the putative anionic nitrene species [(L)Ni(o-tol)(NS(O)tBu)]− represents the preferred pathway for C–N reductive elimination, in keeping with our past study of related sulfonamido complexes." @default.
- W4313252118 created "2023-01-06" @default.
- W4313252118 creator A5020096924 @default.
- W4313252118 creator A5022465458 @default.
- W4313252118 creator A5022665769 @default.
- W4313252118 creator A5057923625 @default.
- W4313252118 creator A5081240667 @default.
- W4313252118 creator A5086367360 @default.
- W4313252118 date "2022-12-27" @default.
- W4313252118 modified "2023-10-16" @default.
- W4313252118 title "Nickel-Catalyzed N-Arylation of Sulfinamides: A Comparative Study versus Analogous Sulfonamide Cross-Couplings" @default.
- W4313252118 cites W1970151326 @default.
- W4313252118 cites W1976355127 @default.
- W4313252118 cites W1996768696 @default.
- W4313252118 cites W2030687529 @default.
- W4313252118 cites W2044290756 @default.
- W4313252118 cites W2109148395 @default.
- W4313252118 cites W2309516451 @default.
- W4313252118 cites W2312526332 @default.
- W4313252118 cites W2332188485 @default.
- W4313252118 cites W2342695428 @default.
- W4313252118 cites W2418896591 @default.
- W4313252118 cites W2579151545 @default.
- W4313252118 cites W2611816409 @default.
- W4313252118 cites W2737411852 @default.
- W4313252118 cites W2740316833 @default.
- W4313252118 cites W2784913318 @default.
- W4313252118 cites W2809666431 @default.
- W4313252118 cites W2907667022 @default.
- W4313252118 cites W2921319013 @default.
- W4313252118 cites W2947291009 @default.
- W4313252118 cites W2948327457 @default.
- W4313252118 cites W2949633227 @default.
- W4313252118 cites W2952053726 @default.
- W4313252118 cites W2974742065 @default.
- W4313252118 cites W3011362693 @default.
- W4313252118 cites W3012323028 @default.
- W4313252118 cites W3012797041 @default.
- W4313252118 cites W3015376042 @default.
- W4313252118 cites W3137462029 @default.
- W4313252118 cites W3148408953 @default.
- W4313252118 cites W4205556399 @default.
- W4313252118 cites W4210469001 @default.
- W4313252118 cites W4210801797 @default.
- W4313252118 cites W4220653821 @default.
- W4313252118 doi "https://doi.org/10.1021/acs.organomet.2c00545" @default.
- W4313252118 hasPublicationYear "2022" @default.
- W4313252118 type Work @default.
- W4313252118 citedByCount "1" @default.
- W4313252118 countsByYear W43132521182023 @default.
- W4313252118 crossrefType "journal-article" @default.
- W4313252118 hasAuthorship W4313252118A5020096924 @default.
- W4313252118 hasAuthorship W4313252118A5022465458 @default.
- W4313252118 hasAuthorship W4313252118A5022665769 @default.
- W4313252118 hasAuthorship W4313252118A5057923625 @default.
- W4313252118 hasAuthorship W4313252118A5081240667 @default.
- W4313252118 hasAuthorship W4313252118A5086367360 @default.
- W4313252118 hasConcept C118629725 @default.
- W4313252118 hasConcept C145148216 @default.
- W4313252118 hasConcept C155647269 @default.
- W4313252118 hasConcept C161790260 @default.
- W4313252118 hasConcept C171560689 @default.
- W4313252118 hasConcept C178790620 @default.
- W4313252118 hasConcept C178907741 @default.
- W4313252118 hasConcept C185592680 @default.
- W4313252118 hasConcept C21951064 @default.
- W4313252118 hasConcept C2778815869 @default.
- W4313252118 hasConcept C2780263894 @default.
- W4313252118 hasConcept C2781039511 @default.
- W4313252118 hasConcept C2781076698 @default.
- W4313252118 hasConcept C38489247 @default.
- W4313252118 hasConcept C504270822 @default.
- W4313252118 hasConcept C544153396 @default.
- W4313252118 hasConcept C71240020 @default.
- W4313252118 hasConceptScore W4313252118C118629725 @default.
- W4313252118 hasConceptScore W4313252118C145148216 @default.
- W4313252118 hasConceptScore W4313252118C155647269 @default.
- W4313252118 hasConceptScore W4313252118C161790260 @default.
- W4313252118 hasConceptScore W4313252118C171560689 @default.
- W4313252118 hasConceptScore W4313252118C178790620 @default.
- W4313252118 hasConceptScore W4313252118C178907741 @default.
- W4313252118 hasConceptScore W4313252118C185592680 @default.
- W4313252118 hasConceptScore W4313252118C21951064 @default.
- W4313252118 hasConceptScore W4313252118C2778815869 @default.
- W4313252118 hasConceptScore W4313252118C2780263894 @default.
- W4313252118 hasConceptScore W4313252118C2781039511 @default.
- W4313252118 hasConceptScore W4313252118C2781076698 @default.
- W4313252118 hasConceptScore W4313252118C38489247 @default.
- W4313252118 hasConceptScore W4313252118C504270822 @default.
- W4313252118 hasConceptScore W4313252118C544153396 @default.
- W4313252118 hasConceptScore W4313252118C71240020 @default.
- W4313252118 hasFunder F4320321629 @default.
- W4313252118 hasFunder F4320334593 @default.
- W4313252118 hasIssue "14" @default.
- W4313252118 hasLocation W43132521181 @default.
- W4313252118 hasOpenAccess W4313252118 @default.
- W4313252118 hasPrimaryLocation W43132521181 @default.
- W4313252118 hasRelatedWork W1968432560 @default.