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- W4313252207 endingPage "112891" @default.
- W4313252207 startingPage "112891" @default.
- W4313252207 abstract "In this work, a series of Co catalysts (namely Co@NC) was designed and developed from the thermal treatment of ZIF-67. Through extensive screening of various parameters, Co@NC700-H2/Ar exhibited the best catalytic performance in the acceptorless alcohol dehydrogenation to carboxylic acids. It was worth noting that Co@NC700-H2/Ar enabled the efficient synthesis of various aromatic and aliphatic carboxylic acids in moderate to high yields. Besides, it was recyclable for 9 consecutive cycles without activity decay. Moreover, the effects of pyrolysis conditions on the catalytic performance of the resulting materials were thoroughly examined, and the rationale for the superiority of Co@NC700-H2/Ar over the other prepared materials was also provided. Specifically, the pyrolysis atmosphere applying 95% of Ar gas and 5% of H2 gas (H2/Ar) resulted in the generation of ideal porosity and carbon nanotubes (CNTs), while utilizing 700 °C as the optimized pyrolysis temperature was ascribed to the comprehensive evaluation of materials crystallinity and defective structures. Furthermore, additional insights were gained by systematically exploring the oxidation states of Co in different catalysts. It was proposed that the Co–N species played a crucial role in this catalysis, while the contribution of other Co species, including Co0 and Co–O, could not be neglected. Finally, a plausible reaction mechanism was proposed based on the above observations and related literature reports." @default.
- W4313252207 created "2023-01-06" @default.
- W4313252207 creator A5001883843 @default.
- W4313252207 creator A5021629538 @default.
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- W4313252207 creator A5050692462 @default.
- W4313252207 creator A5072240075 @default.
- W4313252207 creator A5086846159 @default.
- W4313252207 date "2023-01-01" @default.
- W4313252207 modified "2023-10-16" @default.
- W4313252207 title "Rational design of cobalt catalysts embedded in N-Doped carbon for the alcohol dehydrogenation to carboxylic acids" @default.
- W4313252207 cites W1893178317 @default.
- W4313252207 cites W1917525767 @default.
- W4313252207 cites W1968860517 @default.
- W4313252207 cites W1983282846 @default.
- W4313252207 cites W1992478403 @default.
- W4313252207 cites W2001037711 @default.
- W4313252207 cites W2011262630 @default.
- W4313252207 cites W2019517999 @default.
- W4313252207 cites W2025925068 @default.
- W4313252207 cites W2032142610 @default.
- W4313252207 cites W2063529381 @default.
- W4313252207 cites W2089649385 @default.
- W4313252207 cites W2115959481 @default.
- W4313252207 cites W2144828032 @default.
- W4313252207 cites W2163535530 @default.
- W4313252207 cites W2167367493 @default.
- W4313252207 cites W2297046859 @default.
- W4313252207 cites W2317004216 @default.
- W4313252207 cites W2323271474 @default.
- W4313252207 cites W2330653942 @default.
- W4313252207 cites W2332259280 @default.
- W4313252207 cites W2395768475 @default.
- W4313252207 cites W2433574004 @default.
- W4313252207 cites W2503506498 @default.
- W4313252207 cites W2509971510 @default.
- W4313252207 cites W2512427141 @default.
- W4313252207 cites W2598014817 @default.
- W4313252207 cites W2695378732 @default.
- W4313252207 cites W2734966025 @default.
- W4313252207 cites W2746095059 @default.
- W4313252207 cites W2779121503 @default.
- W4313252207 cites W2786875283 @default.
- W4313252207 cites W2789550173 @default.
- W4313252207 cites W2796351319 @default.
- W4313252207 cites W2809040161 @default.
- W4313252207 cites W2895311586 @default.
- W4313252207 cites W2905933671 @default.
- W4313252207 cites W2906148388 @default.
- W4313252207 cites W2922387151 @default.
- W4313252207 cites W2934443057 @default.
- W4313252207 cites W2944351350 @default.
- W4313252207 cites W2951044014 @default.
- W4313252207 cites W2952691260 @default.
- W4313252207 cites W2953116540 @default.
- W4313252207 cites W2971609872 @default.
- W4313252207 cites W2986761410 @default.
- W4313252207 cites W2997100143 @default.
- W4313252207 cites W2998674331 @default.
- W4313252207 cites W3000161137 @default.
- W4313252207 cites W3006014288 @default.
- W4313252207 cites W3006423923 @default.
- W4313252207 cites W3010434743 @default.
- W4313252207 cites W3016846829 @default.
- W4313252207 cites W3026342597 @default.
- W4313252207 cites W3033983483 @default.
- W4313252207 cites W3043856041 @default.
- W4313252207 cites W3045708008 @default.
- W4313252207 cites W3047878299 @default.
- W4313252207 cites W3082178077 @default.
- W4313252207 cites W3093004279 @default.
- W4313252207 cites W3111664099 @default.
- W4313252207 cites W3112438182 @default.
- W4313252207 cites W3112902635 @default.
- W4313252207 cites W3117786283 @default.
- W4313252207 cites W3126538415 @default.
- W4313252207 cites W3129258171 @default.
- W4313252207 cites W3131900893 @default.
- W4313252207 cites W3136975105 @default.
- W4313252207 cites W3164588247 @default.
- W4313252207 cites W3168742652 @default.
- W4313252207 cites W3188102921 @default.
- W4313252207 cites W3197130187 @default.
- W4313252207 cites W3202759267 @default.
- W4313252207 cites W3206426104 @default.
- W4313252207 cites W3211337823 @default.
- W4313252207 cites W3217044274 @default.
- W4313252207 cites W4205168629 @default.
- W4313252207 cites W4206022792 @default.
- W4313252207 cites W4211110200 @default.
- W4313252207 cites W4282838251 @default.
- W4313252207 cites W4283399119 @default.
- W4313252207 cites W4293059872 @default.
- W4313252207 cites W4296488349 @default.
- W4313252207 doi "https://doi.org/10.1016/j.mcat.2022.112891" @default.