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- W4313255429 startingPage "2209483" @default.
- W4313255429 abstract "Ultrahigh-Ni layered oxides are proposed as promising cathodes to fulfill the range demand of electric vehicles; yet, they are still haunted by compromised cyclability and thermal robustness. State-of-the-art surface coating has been applied to solve the instability via blocking the physical contact between the electrolyte and the highly active Ni4+ ions on the cathode surface, but it falls short in handling the chemo-physical mobility of the oxidized lattice oxygen ions in the cathode. Herein, a direct regulation strategy is proposed to accommodate the highly active anionic redox within the solid phase. By leveraging the stable oxygen vacancies/interstitials in a lithium and oxygen dual-ion conductor (layered perovskite La4 NiLiO8 ) coating layer, the reactivity of the surface lattice oxygen ion is dramatically restrained. As a result, the oxygen release from the lattice is suppressed, as well as the undesired irreversible phase transition and intergranular mechanical cracking. Meanwhile, the introduced dual-ion conductor can also facilitate lithium-ion diffusion kinetics and electronic conductivity on the particle surface. This work demonstrates that accommodating the anionic redox chemistry by dual-ion conductors is an effective strategy for capacity versus stability juggling of the high-energy cathodes." @default.
- W4313255429 created "2023-01-06" @default.
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- W4313255429 date "2023-01-31" @default.
- W4313255429 modified "2023-10-12" @default.
- W4313255429 title "Regulating Surface Oxygen Activity by Perovskite‐Coating‐Stabilized Ultrahigh‐Nickel Layered Oxide Cathodes" @default.
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- W4313255429 doi "https://doi.org/10.1002/adma.202209483" @default.
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