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• W4313259323 endingPage "SD1021" @default.
• W4313259323 startingPage "SD1021" @default.
• W4313259323 abstract "Abstract MnSi 1.7 nanosheet bundles with an improved homogeneous composition were synthesized by annealing from CaSi 2 crystal powders with MnCl 2 in molten salt. The MnSi and Si phases were formed at the initial stage of the synthesis with an inhomogeneous Mn distribution within the nanosheet bundles. Subsequently, the phases were transformed into MnSi 1.7 with an improved homogeneous Mn distribution within them for 10 h annealing in the molten salt. The formation of multiple Mn-silicide phases and remarkable improvement in the structural homogeneity of the MnSi 1.7 nanosheet bundles were discussed in terms of the reactions of Mn or Si with chloride compounds, decomposition of chlorides at elevated temperatures, phase selection of multiple silicide phases, shrinkage of the volume from Si to MnSi 1.7 , and dominant diffusion species. Multiple growth variants of the MnSi 1.7 domains were stacked in the nanosheets. For comparison, the growth in a deliquescent environment realized by NH 4 Cl addition was examined." @default.
• W4313259323 created "2023-01-06" @default.
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• W4313259323 date "2023-01-31" @default.
• W4313259323 modified "2023-09-30" @default.
• W4313259323 title "Synthesis of MnSi_1.7 nanosheet bundles from CaSi₂ crystal powders using MnCl₂ in molten salt" @default.
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• W4313259323 doi "https://doi.org/10.35848/1347-4065/acaeb1" @default.
• W4313259323 hasPublicationYear "2023" @default.
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