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• W4313260183 abstract "In this work, we synthesized mesoporous silica nanoparticles (MSNs) and periodic mesoporous organosilica nanoparticles containing bridging groups of ethylene (E-PMO) and phenylene (P-PMO) and compared their adsorption properties using D-limonene (Lim), myrcene (Myr), and cymene (Cym) as model guest molecules. For the selected nanoparticles of ~100 nm in diameter, the loading capacity to the volatile fragrances was in the order of P-PMO < E-PMO < MSN, consistent with the trend of increasing total pore volume. For example, P-PMO, E-PMO, and MSN had a Lim uptake of 42.2 wt%, 47.3 wt%, and 62.7 wt%, respectively, which was close to their theoretical adsorption capacity. Under isothermal thermogravimetric analysis conditions (30 °C, a N2 flow of 1 mL min−1), the lowest fragrance release of ~56% over 24 h was observed for P-PMO, followed by E-PMO (74−80%), and MSN (~89%). The release kinetics of the fragrant molecules from MSN and PMO materials can be well described by first-order and Weibull models, respectively. Moreover, the incorporation of Lim-loaded P-PMO NPs in an aqueous solution of regenerated silk fibroin provided a composite coating material suitable for perishable fruit preservation. The active layer deposited on fruit peels using dip coating showed good preservation efficacy, enabling the shelf-life of mangoes in a highly humid and hot atmosphere (30−35 °C, 75−85% RH) to be extended to 6 days." @default.
• W4313260183 created "2023-01-06" @default.
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• W4313260183 date "2022-12-25" @default.
• W4313260183 modified "2023-10-15" @default.
• W4313260183 title "Encapsulation of Volatile Monoterpene Fragrances in Mesoporous Organosilica Nanoparticles and Potential Application in Fruit Preservation" @default.
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• W4313260183 doi "https://doi.org/10.3390/nano13010104" @default.
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