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• W4313304164 abstract "In this work, a hierarchical ZnS-SnS-Sb2S3@C ([email protected]) submicron box has been successfully prepared via a facile cation-exchange strategy and is used as advanced anode for Li-ion batteries. The composition and morphology of the as-prepared samples are measured by XRD, SEM and TEM, respectively. In addition, the as-synthesized hollow [email protected] architecture delivers a rate capability of 1001, 862, 765, 621, and 419 mAh g−1 at 0.2, 0.5, 1.0, 2.0, and 4.0 A g−1, respectively, and maintains reversible specific capacity of 581 mAh g−1 after 100 cycles at 1.0 A g−1 with the high CE value around almost 100%. Since 1 mol Sb2S3 could hold 4.8 times more Li+ ions than ZnS, the as-synthesized [email protected] delivers 2∼3 times more specific capacity than the un-treated [email protected] sample without cation-exchange during electrochemical testing. Moreover, the cycled [email protected] could maintain a relatively complete microscopic morphology of the submicron box with a lower electrode expansion rate of ∼131%. Owing to synergistic effects between ZnS-SnS-Sb2S3, such as stable structure from ZnS, faster ionic conductivity from SnS and higher capacity from Sb2S3 (theoretically 947 mAh/g), [email protected] anode showed excellent electrochemical enhancements as using for LIBs anode. Therefore, the cation exchange strategy should be a facile way to improve the rate performance and cycle stability of multi-metals sulfide composites." @default.
• W4313304164 created "2023-01-06" @default.
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• W4313304164 date "2023-01-30" @default.
• W4313304164 modified "2023-09-29" @default.
• W4313304164 title "A Facile Cation‐Exchange Strategy for ZnS‐SnS‐Sb ₂ S ₃ @C Submicron Box as Advanced Anode for Li‐Ion Batteries" @default.
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• W4313304164 doi "https://doi.org/10.1002/cnma.202200540" @default.
• W4313304164 hasPublicationYear "2023" @default.
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