FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4313305144> ?p ?o ?g. }

• W4313305144 endingPage "392" @default.
• W4313305144 startingPage "379" @default.
• W4313305144 abstract "The extent to which altered glass formation behavior in block copolymers and layered polymers results from local compositional mixing vs from longer-ranged dynamical correlations has long been unresolved. Here, we perform molecular dynamics simulations at model polymer–polymer interfaces to understand the relative roles of these mechanisms. Results indicate a crossover from the high-χ regime, where near-interface Tg alterations are driven purely by dynamical gradient effects, to the low-χ regime, where both local mixing and dynamical correlations play a role. Observed Tg gradient ranges are asymmetric, exceed the range of composition gradients, and modestly grow with decreasing χ. These results provide new insight into the design of nanostructured polymers with targeted local dynamics. They also emphasize an apparent dichotomy between many studies, including ours, pointing toward Tg gradient ranges on the order of 10 nm, and a second set of studies reporting on longer ranges up to hundreds of nanometers." @default.
• W4313305144 created "2023-01-06" @default.
• W4313305144 creator A5055785642 @default.
• W4313305144 creator A5090428395 @default.
• W4313305144 date "2022-12-30" @default.
• W4313305144 modified "2023-10-01" @default.
• W4313305144 title "Combined Mixing and Dynamical Origins of <i>T</i>_g Alterations Near Polymer–Polymer Interfaces" @default.
• W4313305144 cites W1835113622 @default.
• W4313305144 cites W1884139160 @default.
• W4313305144 cites W1912876664 @default.
• W4313305144 cites W1963652484 @default.
• W4313305144 cites W1966074483 @default.
• W4313305144 cites W1969894174 @default.
• W4313305144 cites W1971466642 @default.
• W4313305144 cites W1973942854 @default.
• W4313305144 cites W1974716751 @default.
• W4313305144 cites W1978667280 @default.
• W4313305144 cites W1979649598 @default.
• W4313305144 cites W1980965529 @default.
• W4313305144 cites W1981130424 @default.
• W4313305144 cites W1983525413 @default.
• W4313305144 cites W1988320685 @default.
• W4313305144 cites W1988614057 @default.
• W4313305144 cites W1991346562 @default.
• W4313305144 cites W1997824065 @default.
• W4313305144 cites W2000772229 @default.
• W4313305144 cites W2000853705 @default.
• W4313305144 cites W2002115258 @default.
• W4313305144 cites W2003949305 @default.
• W4313305144 cites W2006621073 @default.
• W4313305144 cites W2007661283 @default.
• W4313305144 cites W2008867205 @default.
• W4313305144 cites W2017293864 @default.
• W4313305144 cites W2018789905 @default.
• W4313305144 cites W2019465613 @default.
• W4313305144 cites W2020627046 @default.
• W4313305144 cites W2028264277 @default.
• W4313305144 cites W2031252615 @default.
• W4313305144 cites W2035386512 @default.
• W4313305144 cites W2038502132 @default.
• W4313305144 cites W2042922587 @default.
• W4313305144 cites W2044151926 @default.
• W4313305144 cites W2046097259 @default.
• W4313305144 cites W2046571539 @default.
• W4313305144 cites W2047145226 @default.
• W4313305144 cites W2050027062 @default.
• W4313305144 cites W2050653249 @default.
• W4313305144 cites W2051712852 @default.
• W4313305144 cites W2053539104 @default.
• W4313305144 cites W2057009283 @default.
• W4313305144 cites W2057956576 @default.
• W4313305144 cites W2058284592 @default.
• W4313305144 cites W2058811066 @default.
• W4313305144 cites W2062149030 @default.
• W4313305144 cites W2066992219 @default.
• W4313305144 cites W2068936354 @default.
• W4313305144 cites W2070398505 @default.
• W4313305144 cites W2070755931 @default.
• W4313305144 cites W2073109526 @default.
• W4313305144 cites W2075328342 @default.
• W4313305144 cites W2080455675 @default.
• W4313305144 cites W2085079102 @default.
• W4313305144 cites W2085264882 @default.
• W4313305144 cites W2086194992 @default.
• W4313305144 cites W2089124058 @default.
• W4313305144 cites W2090346674 @default.
• W4313305144 cites W2090627946 @default.
• W4313305144 cites W2100151471 @default.
• W4313305144 cites W2106427547 @default.
• W4313305144 cites W2106480499 @default.
• W4313305144 cites W2120449835 @default.
• W4313305144 cites W2126114443 @default.
• W4313305144 cites W2130608438 @default.
• W4313305144 cites W2134058417 @default.
• W4313305144 cites W2141075684 @default.
• W4313305144 cites W2149159066 @default.
• W4313305144 cites W2153434446 @default.
• W4313305144 cites W2153668263 @default.
• W4313305144 cites W2155124158 @default.
• W4313305144 cites W2159084721 @default.
• W4313305144 cites W2219037287 @default.
• W4313305144 cites W2278515130 @default.
• W4313305144 cites W2314200092 @default.
• W4313305144 cites W2314659567 @default.
• W4313305144 cites W2315663659 @default.
• W4313305144 cites W2317234974 @default.
• W4313305144 cites W2317740962 @default.
• W4313305144 cites W2320186801 @default.
• W4313305144 cites W2320609002 @default.
• W4313305144 cites W2321520710 @default.
• W4313305144 cites W2321879710 @default.
• W4313305144 cites W2323695371 @default.
• W4313305144 cites W2327119132 @default.
• W4313305144 cites W2333824488 @default.
• W4313305144 cites W2521639697 @default.
• W4313305144 cites W2531825475 @default.
• W4313305144 cites W2534125256 @default.
• W4313305144 cites W2586732691 @default.

• next