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- W4313305268 abstract "Ligand-stabilized gold nanoparticles (tetrakis(hydroxymethyl)phosphonium chloride-Au, citrate-Au, cetrimonium bromide-Au) were synthesized and mixed with several weak-base solids (barium carbonate, Amberlite IRA-900) and acidic solid (Dowex 50WX2 resin). Those catalysts were applied for the oxidation of benzyl alcohol in water at 80 oC. Almost ligand-stabilized Au nanoparticles/weak-base solids showed good conversion of benzyl alcohol and high selectivity of benzoic acid, whereas ligand-stabilized Au nanoparticles/acidic solid were catalytically inactive. Nanoparticles were characterized by transmission electron microscopy, zetapotential measurement, and dynamic light scattering. The catalytic activity and product selectivity were determined by using a gas chromatography coupled with a mass selective detector. Our study suggests that the oxidation reaction in water could be catalyzed by gold with the presence of weak-base solids." @default.
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- W4313305268 date "2022-10-12" @default.
- W4313305268 modified "2023-10-16" @default.
- W4313305268 title "Oxidation of benzyl alcohol catalyzed by ligand-stabilized Au nanoparticles in the presence of weak bases" @default.
- W4313305268 doi "https://doi.org/10.51316/jca.2022.043" @default.
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