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- W4313305394 abstract "In this work, two new three-dimensional Co(II) metal-organic frameworks (MOFs), {[Co2(TFBA)(4,4′-bpy)H2O]·5DMF·7H2O}n (CoMOF-1) and {[Co2(TFBA)(bpen)H2O] ·6DMF·6H2O }n (CoMOF-2) (H3TFBA = tris(3′-F-4′-carb oxybiphenyl)amine, 4,4′-bpy = 4,4′-bipyridine, bpen = trans-1,2-bis(4-pyridyl)ethene) were constructed by a solvothermal method. Both CoMOF-1 and CoMOF-2 displayed similar 3D frameworks with the 2, 3, 4, 6-c net topology based on dinuclear [Co2O8] units. The powder X-ray diffraction (PXRD) results and thermogravimetric analysis (TGA) proved that CoMOF-1 and CoMOF-2 have good structural and thermal stability. As we expected, the luminescence sensing investigations demonstrated that CoMOF-1 and CoMOF-2 could be considered as promising luminescent sensors toward Cu2+, Fe3+ and Cr2O72− ions via a quenching effect, with high sensitivity and good reusability. Additionally, the possible luminescent quenching reasons were systematically studied by UV spectroscopy, X-ray photoelectron spectroscopy (XPS), IR spectra and PXRD patterns." @default.
- W4313305394 created "2023-01-06" @default.
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- W4313305394 date "2023-03-01" @default.
- W4313305394 modified "2023-10-16" @default.
- W4313305394 title "Efficient detection of Cu2+, Fe3+ and Cr2O72− in aqueous solution using two new Co(II) luminescent metal-organic frameworks" @default.
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- W4313305394 doi "https://doi.org/10.1016/j.poly.2022.116278" @default.
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