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- W4313306427 abstract "Abstract The biradical [⋅P( μ ‐N‐ t Bu Ph 3 C) 2 P⋅] ( 6 T) can be generated by reduction of a cyclic dichlorophosphane, [ClP( μ ‐N‐ t Bu Ph 3 C) 2 PCl], utilizing magnesium. If this biradical is treated with alkynes, e. g. tolan, Ph−C≡C−Ph, the addition product, a [2.1.1.] bicyclic species, [P( μ ‐N‐ t Bu Ph 3 C) 2 P(Ph−C=C−Ph)] ( 7 ), is obtained. However, if the reduction process with magnesium is carried out in the presence of tolan the reaction mixture finds a different reaction channel, ultimately yielding a magnesium(II) double salt, including a [Mg(THF) 2 ] 2+ cation with a [ t Bu Ph 3 C−N−P−N−C t Bu Ph 3 ] − and a novel tolan‐stabilized [(PhC=CPh)P−N−P(PhC=CPh)] − anion as counterions. This novel anion can also be conceived as anionic [2.2.1] bicycle with a [N] − ion trans ‐annular bridging a 1,4‐diphosphabenzene." @default.
- W4313306427 created "2023-01-06" @default.
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- W4313306427 date "2023-01-09" @default.
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- W4313306427 title "The Sequence Makes the Difference: On the Reaction of Phosphorus‐centered Biradical [⋅P(<i>μ</i>‐N‐<sup><i>t</i>Bu</sup>Ph<sub>3</sub>C)<sub>2</sub>P⋅] with Tolan" @default.
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- W4313306427 doi "https://doi.org/10.1002/zaac.202200355" @default.
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